Copper;pyridine;sulfate | 15322-09-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Copper;pyridine;sulfate
• CAS: 15322-09-5；92275-44-0
• 化学式: C₅H₅N*Cu*O₄S
• 分子量: 238.711
• InChiKey: BKHMEJJDSMFDFK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.26
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  102
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  Copper;pyridine;sulfate 以 neat (no solvent) 为溶剂， 生成 吡啶 、 copper(II) sulfate
  参考文献：
  名称：

  Joergensen, S. M., Journal fur praktische Chemie (Leipzig 1954), 1886, vol. 33, p. 502 - 504

  摘要：

  DOI：
• 作为产物：
  描述：

  {Cupy4}SO4 以 吡啶 为溶剂， 生成 Copper;pyridine;sulfate
  参考文献：
  名称：

  Ragno, M.; Vadala, L., Gazzetta Chimica Italiana, 1935, vol. 65, p. 686 - 689

  摘要：

  DOI：

文献信息

• Antimicrobial Activity of Cu(II) and Fe(III) with Pyridine Complexes as Ligands Contrary to Clinical Strains of Bacteria and Fungi Species
  作者：Faridul Islam、Jannat Al Foisal、Mahbubur Rahman、Md Zahidul Islam、Mst. Afsana Mimi、Rasel Habib、Md. Amran Hossain、Likson Chowdhury、Sreebash Chandra Bhattacharjee、Daxiang Cui

  DOI：10.14233/ajchem.2019.22096

  日期：2019.9.10

  In this study, green coloured Cu(II) and red coloured Fe(III) complexes of pyridine were prepared and the elemental characterization confirmed their composition. The pyridine complexes of Cu(II) and Fe(III) were found very interesting and attractive as potential candidates with antimicrobial activity. Along with this, melting point, molar conductivity measurement, magnetic moment determination, electronic and FTIR spectroscopy were also measured to characterize the prepared complexes. Pyridine acts as monodentate which resulted in formation of square planar and octahedral structure of Cu(II) and Fe(III) complexes, respectively with the nitrogen atom pyridine ring by coordination bond. For antimicrobial activity studies Alternaria alternata, Bacillus cerelus, Botrgodiplodia theobromal, Colletotrichums corcolei, Escherichia coli, Fusarium equiseti, Macrophomina phaseolina, Salmonell typhi and Shigella dysenteriae were used. The prepared complexes showed inhibition against mycelial growth. Although the complexes showed satisfactory inhibition against the tested bacteria and fungi species, both of the complexes were comparatively better against bacteria than fungi compared to ligand.

  在这项研究中，制备了吡啶的绿色Cu（II）和红色Fe（III）配合物，并通过元素表征证实了它们的组成。Cu（II）和Fe（III）的吡啶配合物被发现非常有趣和有吸引力，是具有抗微生物活性的潜在候选物。除此之外，还测量了熔点、摩尔电导率、磁矩测定、电子和FTIR光谱以表征制备的配合物。吡啶作为一价配体，通过配位键与吡啶环上的氮原子形成了Cu（II）和Fe（III）配合物的四面体和八面体结构。在抗微生物活性研究中，使用了Alternaria alternata、Bacillus cerelus、Botrgodiplodia theobromal、Colletotrichums corcolei、Escherichia coli、Fusarium equiseti、Macrophomina phaseolina、Salmonell typhi和Shigella dysenteriae。制备的配合物显示出对菌丝生长的抑制作用。虽然这些配合物对测试的细菌和真菌物种都显示出了令人满意的抑制作用，但与配体相比，两种配合物对细菌的抑制作用更好些。
• On some copper(I) perthiocarboxylates and their reactions with tertiary phosphines. Crystal structure of tetra(p-tolyldithiocarboxylato)tetracopper(I), [CuS2C-p-tolyl]4, and of [bis(triphenylphosphine)(p-tolyldithiocarboxylato)copper(I)] triphenylphosphine sulfide, [CuS2C-p-tolyl(PPh3)2]·PPh3S
  作者：Annamaria Camus、Nazario Marsich、Anna Maria Manotti Lanfredi、Franco Ugozzoli

  DOI：10.1016/s0020-1693(00)90120-8

  日期：1989.7

  in which the metal atom is pseudo-tetrahedrally coordinated by two phosphorous atoms from triphenylphosphine ligands and by two sulfur atoms from one chelating p -tolyldithiocarboxylate group. Triphenylphosphine sulfide molecules are also present in the crystals of VIb . The complex autoxidative reactions of some dithiocarboxylates in pyridine, which cause a partial transformation of the sulfur atoms

  摘要在碱性介质中，由相应的醛和多硫化铵高收率地制备了一些高硫羧酸铜（CuS 3 CAr）4（I）（Ia，ArPh； Ib，Ar对甲苯基）。通过使它们与三苯基膦以不同的比例反应，形成了PPh 3 S，可以分离出以下系列的产物：[[（CuS 3 CAr）2（CuS 2 -CAr）2] py 2（II）; [CuS 2 CAr] 4（III）; [（CuS 2 CAr）4-（PPh 3）2]（IV）; [CuS 2 CAr（PPh 3）2]（V）。在对甲苯基的情况下，还获得了复合物[CuS 2 CAr（PPh 3）2]·PPh 3 S（VIb）。报告了上述化合物的一些重要的IR和NMR（13 C，31 P）数据。化合物IIIb和VIb的晶体结构通过单晶X射线衍射法确定。IIIb晶体为三斜晶系，空间群P 1，a = 13.879（4），b = 10.324（3），c ＝ 13.479（4）A，α＝
• Next Generation Copper Mediators for the Efficient Production of ¹⁸ F‐Labeled Aromatics
  作者：Chris Hoffmann、Niklas Kolks、Daniel Smets、Alexander Haseloer、Benedikt Gröner、Elizaveta A. Urusova、Heike Endepols、Felix Neumaier、Uwe Ruschewitz、Axel Klein、Bernd Neumaier、Boris D. Zlatopolskiy

  DOI：10.1002/chem.202202965

  日期：2023.1.9

  Evaluation of a series of Cu(II) complexes revealed several highly efficient mediators for radiofluorination of aryl boronic and stannyl substrates. After optimization of the reaction conditions, their application enabled preparation of seven PET-tracers in improved radiochemical yields and/or using significantly lower precursor loadings.

  对一系列 Cu(II) 配合物的评估揭示了几种用于芳基硼和锡基底物放射性氟化的高效介质。在优化反应条件后，他们的应用能够制备七种 PET 示踪剂，提高放射化学产量和/或使用显着降低的前体负载。
• Production of hexanitrostilbene (HNS)
  申请人：Secretary of State for Defence in Her Britannic Majesty's Gov. of the United Kingdom of Great Britain and Northern Ireland

  公开号：EP0132990A2

  公开（公告）日：1985-02-13

  A process for the manufacture of 2,2', 4,4', 6,6 - hexanitrostilbene (HNS) from dipicrylethane (DPE) or trinitrotoluene (TNT) which consists of oxidising DPE or TNE substrate in the presence of an aprotic solvent and a basic salt of a carboxylic acid. The acid preferably consists of an ammonium or an alkali metal salt of a monocarboxylic or a dicarboxylic acid. The reaction step consists of heating the substrate and salt dissolved in the solvent to between 15 and 50°C, and contacting the reaction mixture with dry air or oxygen for up to 2 hours. The HNS product is precipitated out by quenching the reaction mixture in acidified water, and is optionally purified by washing first in methanol and then in acetone.

  一种从二丙烯基乙烷（DPE）或三硝基甲苯（TNT）制取 2,2'，4,4'，6,6-己硝基苯乙烯（HNS）的工艺，包括在壬烷溶剂和羧酸的碱性盐存在下氧化 DPE 或 TNE 底物。这种酸最好是单羧酸或二羧酸的铵盐或碱金属盐。反应步骤包括将溶解在溶剂中的底物和盐加热到 15 至 50°C，并将反应混合物与干燥空气或氧气接触最多 2 小时。通过在酸化水中淬灭反应混合物，析出 HNS 产物，并可选择先在甲醇中洗涤，然后在丙酮中净化。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B1, 253, page 571 - 573
  作者：

  DOI：——

  日期：——