[tris(4-methylphenyl)-(3,4,5-trifluorobenzoyl)oxy-λ5-stibanyl] 3,4,5-trifluorobenzoate | 460752-07-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [tris(4-methylphenyl)-(3,4,5-trifluorobenzoyl)oxy-λ5-stibanyl] 3,4,5-trifluorobenzoate
• CAS: 460752-07-2
• 化学式: C₃₅H₂₅F₆O₄Sb
• 分子量: 745.322
• InChiKey: JZGYQQPBTHKWRS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.58
• 重原子数：
  46.0
• 可旋转键数：
  7.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  52.6
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  penta(p-tolyl)antimony(V) 、 [tris(4-methylphenyl)-(3,4,5-trifluorobenzoyl)oxy-λ5-stibanyl] 3,4,5-trifluorobenzoate 以 甲苯 为溶剂， 以96%的产率得到tetra(p-tolyl)antimony 3,4,5-trifluorobenzoate
  参考文献：
  名称：

  摘要：

  Pentaarylantimonies Ar5Sb (Ar = Ph, p-Tol) was reacted with triarylantimony bis(perfluorobenzoate) and bis(3,4,5-trifluorobenzoate) in toluene at elevated temperature to obtain tetraarylantimony fluorobenzoates in 90% yield. Triarylantimony bis(fluorobenzoates) were prepared in an yield of up to 98% from triarylstibine and fluorobenzoic acid by oxidative addition in ether in the presence of hydrogen peroxide.

  DOI：

  10.1023/a:1015439500222
• 作为产物：
  描述：

  三(对甲苯基)锑 、 3,4,5-三氟苯甲酸 在 双氧水 作用下， 以 乙醚 、 水 为溶剂， 以99%的产率得到[tris(4-methylphenyl)-(3,4,5-trifluorobenzoyl)oxy-λ5-stibanyl] 3,4,5-trifluorobenzoate
  参考文献：
  名称：

  摘要：

  Pentaarylantimonies Ar5Sb (Ar = Ph, p-Tol) was reacted with triarylantimony bis(perfluorobenzoate) and bis(3,4,5-trifluorobenzoate) in toluene at elevated temperature to obtain tetraarylantimony fluorobenzoates in 90% yield. Triarylantimony bis(fluorobenzoates) were prepared in an yield of up to 98% from triarylstibine and fluorobenzoic acid by oxidative addition in ether in the presence of hydrogen peroxide.

  DOI：

  10.1023/a:1015439500222