2-furaldehyde thiosemicarbazone zinc(II) | 79766-98-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 2-furaldehyde thiosemicarbazone zinc(II)
• CAS: 79766-98-6
• 化学式: C₁₂H₁₂N₆O₂S₂Zn
• 分子量: 401.788
• InChiKey: VATRMXWYFFLUCE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  furan-2-aldehyde thiosemicarbazone 、 zinc diacetate 以 乙醇 、 水 为溶剂， 以82%的产率得到2-furaldehyde thiosemicarbazone zinc(II)
  参考文献：
  名称：

  Chatterjee; Duggal; Agarwala, Journal of the Indian Chemical Society, 1989, vol. 66, # 8-10, p. 550 - 557

  摘要：

  DOI：

文献信息

• Transition Metal Complexes of Furan‐2‐aldehyde Thiosemicarbazone
  作者：Maliyeckal R. Prathapachandra Kurup、Marthakutty Joseph

  DOI：10.1081/sim-120023500

  日期：2003.1.8

  Cu(II), Ni(II), Zn(II), and Co(III) complexes of furan-2-aldehyde thiosemicarbazone (HL) have been synthesized and are characterized by elemental analyses, molar conductance measurements, magnetic susceptibility measurements, UV-Vis, IR, (1)H NMR and EPR spectra. The molar conductivities show that all of the complexes are non-electrolytes. The IR spectra suggest coordination of the thiosemicarbazone to the metal through azomethine nitrogen and thiolate sulfur atoms. The furan oxygen appears not to be coordinated in all complexes. The complexes have the formulas Cu(2)L(2)Cl(2), NiL(2), ZnL(2) and CoL(3) where L corresponds to the anionic thiosemicarbazone.
• Aravindakshan, K. K.; Nair, C. G. R., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1981, vol. 20, # 7, p. 684 - 687
  作者：Aravindakshan, K. K.、Nair, C. G. R.

  DOI：——

  日期：——