2-(2-hydroxy-3-(m-methyl-benzoyl)-5-methyl-phenyl)benzotriazole | 1220631-16-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(2-hydroxy-3-(m-methyl-benzoyl)-5-methyl-phenyl)benzotriazole
• 英文别名: [3-(Benzotriazol-2-yl)-2-hydroxy-5-methylphenyl]-(3-methylphenyl)methanone
• CAS: 1220631-16-2
• 化学式: C₂₁H₁₇N₃O₂
• 分子量: 343.385
• InChiKey: KFIJAHVDAXRWHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  68
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-(2H-1,2,3-Benzotriazol-2-yl)-4-methylphenyl 3-methylbenzoate 在 aluminum (III) chloride 盐酸 、 sodium hydroxide 作用下， 以 水 为溶剂， 反应 2.0h， 生成 2-(2-hydroxy-3-(m-methyl-benzoyl)-5-methyl-phenyl)benzotriazole
  参考文献：
  名称：

  Ultraviolet light absorbing ketones of 2-(2-Hydroxyphenyl) benzotriazole

  摘要：

  本发明涉及紫外线吸收化合物，它们的制备以及在涂料、塑料和局部应用产品中作为保护剂和稳定剂的用途。该化合物是式I中的2-(2-羟基苯基)苯并三唑的酮衍生物，其中R1是氢原子、卤素原子、1至4个碳原子的直链或支链低级烷基或低级烷氧基；R2是未取代或取代的芳基基团或未取代或取代的1至18个碳原子的直链或支链烷基或5至6个碳原子的环烷基团；R3是直链或支链烷基或烷基芳基基团或烷氧基或苯基或被烷基、环烷基、羧基烷氧基、氯或芳基烷基基团取代的苯基。

  公开号：

  US20100086500A1

文献信息

• Ultraviolet light absorbing ketones of 2-(2-hydroxyhenyl) benzotriazole
  申请人：Chang Chia-Hu

  公开号：US20110038816A1

  公开（公告）日：2011-02-17

  The invention relates to ultraviolet light absorbing compounds, their preparation and uses as protective agents and stabilizers in coatings, plastics and topically applied products. The compounds are ketone derivatives of 2-(2-hydroxyphenol)benzotriazole of formula I, where R 1 is hydrogen atom, or a halogen atom, or a straight-chain or branched lower alkyl or lower alkoxy of 1 to 4 carbon atoms; R 2 is an unsubtituted or substituted aryl group or an unsubstituted or substituted straight-chain or branched alkyl having 1 to 18 carbon atoms or a cycloaliphatic group having 5 to 6 carbon atoms; and R 3 is a straight-chain or branched alkyl or alkylaryl group or alkoxyl or phenyl or phenyl substituted with alkyl, cycloalkyl, carboalkoxy, chlorine or arylalkyl groups.
• Ultraviolet light absorbing compounds based on benzyl substituted 2-(2- hydroxyphenyl) benzotriazoles
  申请人：Chang Chia-Hu

  公开号：US20120329885A1

  公开（公告）日：2012-12-27

  The present invention relates to ultraviolet light absorbing compounds having the formula I and compositions containing these compounds in combination with polymers and/or carriers: wherein; R 1 is hydrogen or a halogen atom or a straight-chain or branched alkyl group, an alkoxy group or a carboalkoxy group; R 2 and R 2′ can be the same or different and individually are selected from the group consisting of hydrogen, an unsubstituted or substituted straight-chain or branched alkyl group, an alkoxy group, a carboxyalkyl group, a carboalkoxy, a carboxyl group, an hydroxyl group, and a halogen atom. R 3 , R 4 and R 5 can be the same or different and individually are selected from the group consisting of hydrogen, a straight-chain or branched alkyl group, an alkylaryl group, an alkoxy group, a phenyl or substituted phenyl group, a cycloalkyl group, a carboalkoxy group, an arylalkyl group, an hydroxyl group and a halogen atom.
• US7847103B2
  申请人：——

  公开号：US7847103B2

  公开（公告）日：2010-12-07
• US8163934B2
  申请人：——

  公开号：US8163934B2

  公开（公告）日：2012-04-24
• Ultraviolet light absorbing ketones of 2-(2-Hydroxyphenyl) benzotriazole
  申请人：Chang Chia-Hu

  公开号：US20100086500A1

  公开（公告）日：2010-04-08

  The invention relates to ultraviolet light absorbing compounds, their preparation and uses as protective agents and stabilizers in coatings, plastics and topically applied products. The compounds are ketone derivatives of 2-(2-hydroxyphenol) benzotriazole of formula I, where R 1 is hydrogen atom, or a halogen atom, or a straight-chain or branched lower alkyl or lower alkoxy of 1 to 4 carbon atoms; R 2 is an unsubtituted or substituted aryl group or an unsubstituted or substituted straight-chain or branched alkyl having 1 to 18 carbon atoms or a cycloaliphatic group having 5 to 6 carbon atoms; and R 3 is a straight-chain or branched alkyl or alkylaryl group or alkoxyl or phenyl or phenyl substituted with alkyl, cycloalkyl, carboalkoxy, chlorine or arylalkyl groups.

  本发明涉及紫外线吸收化合物，它们的制备以及在涂料、塑料和局部应用产品中作为保护剂和稳定剂的用途。该化合物是式I中的2-(2-羟基苯基)苯并三唑的酮衍生物，其中R1是氢原子、卤素原子、1至4个碳原子的直链或支链低级烷基或低级烷氧基；R2是未取代或取代的芳基基团或未取代或取代的1至18个碳原子的直链或支链烷基或5至6个碳原子的环烷基团；R3是直链或支链烷基或烷基芳基基团或烷氧基或苯基或被烷基、环烷基、羧基烷氧基、氯或芳基烷基基团取代的苯基。