4,10-Bis(2-methoxy-6-propan-2-yloxyphenyl)-3,7,11-trithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene | 1353974-87-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 4,10-Bis(2-methoxy-6-propan-2-yloxyphenyl)-3,7,11-trithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene
• CAS: 1353974-87-4
• 化学式: C₂₈H₂₈O₄S₃
• 分子量: 524.726
• InChiKey: KHDARMKKOCGMHW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  35
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  122
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  2-异丙氧基-6-甲氧基苯基硼酸 、 2,6-二溴二噻吩[3,2-b:2',3'-d]噻吩 在 2-双环己基膦-2',6'-二甲氧基联苯 、 palladium diacetate potassium phosphate 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 8.0h， 以71%的产率得到4,10-Bis(2-methoxy-6-propan-2-yloxyphenyl)-3,7,11-trithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene
  参考文献：
  名称：

  [EN] NOVEL ORGANIC COMPOUND AND ELECTROCHROMIC DEVICE INCLUDING THE SAME
  [FR] NOUVEAU COMPOSÉ ORGANIQUE ET DISPOSITIF ÉLECTROCHROME LE COMPRENANT

  摘要：

  提供的是由一般式[1]表示的新型电子化合物，具有优异的氧化还原重复性，在漂白时具有高透明度，在可见光区域不显示光学吸收。【其中R1、A、A'和n具有权利要求书中引用的标记。】

  公开号：

  WO2012002185A1

文献信息

• Electrochromic element, optical filter, lens unit, imaging apparatus, and window member
  申请人：CANON KABUSHIKI KAISHA

  公开号：US10444588B2

  公开（公告）日：2019-10-15

  Provided is an electrochromic element, including: a pair of electrodes; and an electrochromic layer disposed between the pair of electrodes and containing a plurality of kinds of organic electrochromic compounds, in which: at least one kind of the plurality of kinds of organic electrochromic compounds includes an organic electrochromic compound having an absorption peak in a wavelength region of 700 nm or more during coloring thereof; and when an optical density in a decolored state thereof is defined as 0, a fluctuation ratio of a transmittance in a wavelength region of from 650 nm or more to 700 nm or less with respect to a central transmittance is within ±15% at an optical density of 0.3.

  提供了一种电致变色元件，包括：一对电极；以及设置在这对电极之间的电致变色层，其中包含多种有机电致变色化合物，其中多种有机电致变色化合物中的至少一种包括在其着色过程中在 700 纳米或更高波长区域具有吸收峰的有机电致变色化合物；当其脱色状态下的光密度定义为 0 时，在光密度为 0 时，从 650 纳米或更高到 700 纳米或更低波长区域的透射率相对于中心透射率的波动比在±15%以内。3.
• ELECTROCHROMIC ELEMENT
  申请人：Canon Kabushiki Kaisha

  公开号：EP2719702B1

  公开（公告）日：2016-05-11
• JP6053438
  申请人：——

  公开号：——

  公开（公告）日：——
• ORGANIC COMPOUND AND ELECTROCHROMIC DEVICE INCLUDING THE SAME
  申请人：Canon Kabushiki Kaisha

  公开号：EP2588484B1

  公开（公告）日：2015-11-04
• ELECTROCHROMIC DEVICE
  申请人：Yamada Kenji

  公开号：US20120314272A1

  公开（公告）日：2012-12-13

  There is provided an EC device having stability against redox reaction cycles, high transparency, i.e., the EC device does not absorb light in the visible region in a bleached state, and having excellent response speed. The electrochromic device includes a pair of electrodes and a composition arranged between the pair of electrodes, the composition containing an electrolyte and an organic electrochromic compound, in which the organic electrochromic compound includes an electrochromic portion that exhibits electrochromic properties and an aromatic ring directly bonded to the electrochromic portion, the electrochromic portion forms one conjugated plane, an atom of the aromatic ring and adjacent to an atom bonded to the electrochromic portion has a substituent having a volume equal to or larger than the volume of a methyl group, and a cathodically electrochromic organic compound is further contained in addition to the organic electrochromic compound.