copper(II)(2,2-bipyridine)(1,2,4-benzenetricarboxylate) | 942485-23-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: copper(II)(2,2-bipyridine)(1,2,4-benzenetricarboxylate)
• CAS: 942485-23-6
• 化学式: C₁₉H₁₃CuN₂O₆
• 分子量: 428.868
• InChiKey: RPAZFUHEJMMLNT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 copper(l) iodide 、 偏苯三酸酐 在 KI 作用下， 以 水 为溶剂， 生成 copper(II)(2,2-bipyridine)(1,2,4-benzenetricarboxylate)
  参考文献：
  名称：

  Self-assembly of two fluorescent supramolecular frameworks constructed from unsymmetrical benzene tricarboxylate and bipyridine

  摘要：

  Two new supramolecular compounds, [Ag(4,4'-bipy)](n) [Ag(HBTC)(n) (1) and [Cu(H2BTC)2,2-bipy)] (2) (HBTC/H2BTC = 1,2,4-benzenetricarboxylate, 4,4'-bipy/2,2'-bipy = 4,4'/2,2'-bipyridine), have been synthesized and characterized by elemental analyses, IR spectra, ultraviolet-visible diffuse reflection integral spectra (UV-Vis DRIS), fluorescent spectra, thermogravimetric analysis and single crystal X-ray diffraction analysis. It is noteworthy that there were two kinds of one-dimensional stairs-chain including cationic [Ag(4,4'-bipy)(n) chain and anionic [Ag(HBTC)(n) chain in 1. Furthermore, a two-dimensional double layer supramolecular framework was constructed through coordination bonds, hydrogen bonds, pi-pi stacking interactions and Ag center dot center dot center dot O weak coordinative interactions. The one-dimensional supramolecular chain of 2 was built from combining mononuclear [Cu(H2BTC)(2,2'-bipy)] by inter- and intramolecular hydrogen bonding interactions. Additionally, the two complexes exhibit intense blue or olivine luminescence at room temperature. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.01.023