potassium;4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane;iodide | 1259546-12-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: potassium;4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane;iodide
• CAS: 1259546-12-7；33636-95-2
• 化学式: C₁₈H₃₆KN₂O₆*I
• 分子量: 542.496
• InChiKey: AAQCULRWJUSYEO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -6.27
• 重原子数：
  28.0
• 可旋转键数：
  0.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  61.86
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  1,4-二碘四氟苯 、 potassium;4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane;iodide 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Halide anion-templated assembly of di- and triiodoperfluorobenzenes into 2D and 3D supramolecular networks

  摘要：

  The single crystal structures of five co-crystals formed by the reaction of different iodide and bromide salts with di- and triiodoperfluorobenzenes (I-ArF) are reported All of these perfluorocarbon-hydrocarbon systems are heteromeric three-component systems wherein the weakly coordinating cations favour the formation of naked halides which function as electron-donors towards the I-ArF modules The analysis of the crystal structures shows that I- I-ArF and Br- I-ArF halogen bonds (XBs) control the self-assembly of the obtained supramolecular architectures 2D and 3D supramolecular networks have been obtained wherein naked iodide and bromide anions act as tri- tetra- or pentadentate nodes The selected examples demonstrate that I-ArF modules can be particularly robust and reliable tectons for XB-based coordination of halide ions and afford supramolecular architectures in a rational and predictable way (C) 2010 Elsevier B V All rights reserved

  DOI：

  10.1016/j.jfluchem.2010.05.004
• 作为产物：
  描述：

  4,7,13,16,21,24-六氧-1,10-二氮双环[8.8.8]二十六烷 在 potassium iodide 作用下， 以 乙酸乙酯 为溶剂， 反应 1.0h， 生成 potassium;4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane;iodide
  参考文献：
  名称：

  Halide anion-templated assembly of di- and triiodoperfluorobenzenes into 2D and 3D supramolecular networks

  摘要：

  The single crystal structures of five co-crystals formed by the reaction of different iodide and bromide salts with di- and triiodoperfluorobenzenes (I-ArF) are reported All of these perfluorocarbon-hydrocarbon systems are heteromeric three-component systems wherein the weakly coordinating cations favour the formation of naked halides which function as electron-donors towards the I-ArF modules The analysis of the crystal structures shows that I- I-ArF and Br- I-ArF halogen bonds (XBs) control the self-assembly of the obtained supramolecular architectures 2D and 3D supramolecular networks have been obtained wherein naked iodide and bromide anions act as tri- tetra- or pentadentate nodes The selected examples demonstrate that I-ArF modules can be particularly robust and reliable tectons for XB-based coordination of halide ions and afford supramolecular architectures in a rational and predictable way (C) 2010 Elsevier B V All rights reserved

  DOI：

  10.1016/j.jfluchem.2010.05.004

文献信息

• Photochemical Synthesis of a Stable Terminal Uranium(VI) Nitride
  作者：Luciano Barluzzi、Rosario Scopelliti、Marinella Mazzanti

  DOI：10.1021/jacs.0c09814

  日期：2020.11.11

  [NBu4][U(OSi(OtBu)3)4(N)], 3, can be prepared upon photolysis with UV light of the U(IV) azide analogue. This is achieved by careful tailoring of the azide precursor and of the reaction conditions. Complex 3 is stable under ambient conditions but reacts readily with electrophiles (H+ and CO).

  迄今为止，已证明无法通过叠氮化物的光解来分离末端氮化铀。在这里，我们报告了孤立终端氮化铀 (VI) 的第二个例子。我们表明，末端氮化物 [NBu4][U(OSi(OtBu)3)4(N)], 3 可以通过 U(IV) 叠氮化物类似物的紫外光光解制备。这是通过仔细调整叠氮化物前体和反应条件来实现的。配合物 3 在环境条件下是稳定的，但很容易与亲电子试剂（H+ 和 CO）反应。
• Template effect of intramolecular hydrogen-bonding in the synthesis of [1.1.1]cryptates
  作者：Rita Annunziata、Fernando Montanari、Silvio Quici、Maria Teresa Vitali

  DOI：10.1039/c39810000777

  日期：——

  monometallated [1.1]diazacoro-nand with diethylene glycol bis(methanesulphonate), as well as with its alkyl substituted derivatives, gives the corresponding[1.1.1]azamacrobicyclic polyethers through a template effect due to NH intramolecular hydrogen-bonding.

  单金属化的[1.1]二氮杂壬二酮与二甘醇双（甲磺酸盐）及其烷基取代的衍生物的缩合，由于NH分子内氢键作用，通过模板效应得到相应的[1.1.1]氮杂双环聚醚。
• Eichbichler, Johann; Peringer, Paul, Chemische Berichte, 1984, vol. 117, # 3, p. 1215 - 1221
  作者：Eichbichler, Johann、Peringer, Paul

  DOI：——

  日期：——
• Solvent dependence of the kinetics of formation and dissociation of cryptate complexes
  作者：B. G. Cox、J. Garcia-Rosas、H. Schneider

  DOI：10.1021/ja00395a010

  日期：1981.3
• Wood, Gordon Walter; Au, Mei-Kuen; Mak, Ning, Canadian Journal of Chemistry, 1980, vol. 58, # 7, p. 681 - 685
  作者：Wood, Gordon Walter、Au, Mei-Kuen、Mak, Ning、Lau, Pui-Yan

  DOI：——

  日期：——