2-Propenoic acid, 2,4-dibromo-6-(1-methylpropyl)phenyl ester | 215805-85-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: 2-Propenoic acid, 2,4-dibromo-6-(1-methylpropyl)phenyl ester
• 英文别名: (2,4-dibromo-6-butan-2-ylphenyl) prop-2-enoate
• CAS: 215805-85-9
• 化学式: C₁₃H₁₄Br₂O₂
• 分子量: 362.06
• InChiKey: JSRXZOZKQIYING-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• [EN] DICARBOXYLIC ACID COMPOUNDS. INORGANIC PARTICLES TREATED WITH THE DICARBOXYLIC ACID COMPOUNDS, AND COMPOSITIONS THEREOF<br/>[FR] COMPOSÉS D'ACIDE DICARBOXYLIQUE, PARTICULES INORGANIQUES TRAITÉES PAR LES COMPOSÉS D'ACIDE DICARBOXYLIQUE ET COMPOSITIONS CORRESPONDANTES
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2021064530A1

  公开（公告）日：2021-04-08

  Described herein is a dicarboxylic acid compound of formula (I): Wherein: R3 comprises an aryl group, R2 is an alkylene group comprising 1 to 6 carbon atoms, n is 0 or 1, R1 is H or CH3, and X is S or NZ, wherein Z is H, an alkyl group comprising 1 to 4 carbon atoms or a phenyl group. Such compounds can be used to modify the surface of inorganic particles. These modified inorganic particles may then be advantageously used in polymerizable resins to increase the refractive index of the resulting composite, while enabling good flow properties of the polymerizable composition

  本文介绍了一种二羧酸化合物，其化学式为（I）：其中：R3包括一个芳基基团，R2是含有1至6个碳原子的烷基基团，n为0或1，R1为H或CH3，X为S或NZ，其中Z为H，含有1至4个碳原子的烷基基团或苯基团。这些化合物可用于修改无机颗粒的表面。然后可以有利地将这些修改后的无机颗粒用于可聚合树脂中，以增加所得复合材料的折射率，同时使可聚合组分具有良好的流动性。
• MICROSTRUCTURED OPTICAL FILMS COMPRISING BIPHENYL DIFUNCTIONAL MONOMERS
  申请人：Invie Judith M.

  公开号：US20080221291A1

  公开（公告）日：2008-09-11

  Optical films having a polymerized microstructured surface are described. The polymerized microstructured surface comprises the reaction product of a polymerizable resin composition comprising 10% to 100 wt-% of at least one biphenyl di(meth)acrylate monomer. The di(meth)acrylate monomer comprises a core biphenyl structure having two aromatic rings connected with a C—C bond. The biphenyl di(meth)acrylate monomer preferably comprises a sufficient amount of ortho and/or meta(meth)acrylate substituents such that the monomer is a liquid at 25° C.

  描述了具有聚合微结构表面的光学薄膜。聚合微结构表面包括聚合物化可树脂组合物的反应产物，该组合物包括10%至100重量％的至少一种联苯二（甲基）丙烯酸酯单体。二（甲基）丙烯酸酯单体包括一个核心联苯结构，其中两个芳香环通过C-C键连接。联苯二（甲基）丙烯酸酯单体优选包括足够量的邻位和/或间位（甲基）丙烯酸酯取代基，使单体在25°C时为液体。
• METHODS OF MAKING MICROSTRUCTURED OPTICAL FILMS COMPRISING BIPHENYL DIFUNCTIONAL MONOMERS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20130149495A1

  公开（公告）日：2013-06-13

  A method of making optical films having a polymerized microstructured surface are described. The polymerized microstructured surface comprises the reaction product of a polymerizable resin composition comprising 10% to 100 wt-% of at least one biphenyl di(meth)acrylate monomer. The di(meth)acrylate monomer comprises a core biphenyl structure having two aromatic rings connected with a C—C bond. The biphenyl di(meth)acrylate monomer preferably comprises a sufficient amount of ortho and/or meta(meth)acrylate substituents such that the monomer is a liquid at 25° C.

  本文描述了一种制备具有聚合微结构表面的光学膜的方法。聚合微结构表面由聚合树脂组成，包括至少10%至100重量％的联苯二（甲基）丙烯酸酯单体。二（甲基）丙烯酸酯单体包括一个核心联苯结构，其具有两个芳香环通过C—C键连接。联苯二（甲基）丙烯酸酯单体最好包括足够的邻位和/或间位（甲基）丙烯酸酯取代基，使得单体在25℃时为液态。
• Polymerizable compositions comprising nanoparticles
  申请人：3M Innovative Properties Co.

  公开号：EP2278363A2

  公开（公告）日：2011-01-26

  Polymerizable compositions comprising nanoparticles particularly useful for brightness enhancing films (30).

  包含纳米颗粒的可聚合组合物，尤其适用于增亮薄膜 (30)。
• Photopolymerizable compositions including a urethane component and a monofunctional reactive diluent, articles, and methods
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US11389276B2

  公开（公告）日：2022-07-19

  The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes at least one urethane component, at least one monofunctional reactive diluent, an initiator, and optionally an inhibitor. The present disclosure also provides an article including the reaction product of the photopolymerizable composition. Further, the present disclosure provides a method of making an article. The method includes (i) providing a photopolymerizable composition and (ii) selectively curing the photopolymerizable composition to form an article. The method optionally also includes (iii) curing unpolymerized urethane component and/or reactive diluent remaining after step (ii). Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

  本公开提供了一种可光聚合组合物。该可光聚合组合物包括至少一种聚氨酯成分、至少一种单官能团反应性稀释剂、引发剂和可选的抑制剂。本公开还提供了一种包括可光聚合组合物反应产物的物品。此外，本公开还提供了一种制造物品的方法。该方法包括(i)提供可光聚合组合物和(ii)选择性固化可光聚合组合物以形成制品。该方法可选地还包括(iii)固化步骤(ii)后剩余的未聚合聚氨酯成分和/或活性稀释剂。此外，还提供了一些方法，包括由具有一个或多个处理器的制造设备接收数字对象，该数字对象包括指定物品的数据；以及利用制造设备通过增材制造工艺根据数字对象生成物品。还提供了一种系统，包括显示物品三维模型的显示器；以及一个或多个处理器，这些处理器响应用户选择的三维模型，使三维打印机创建物品的物理对象。