1,8-bis(thiazolyloxy)-9,10-anthracenedione | 953793-75-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,8-bis(thiazolyloxy)-9,10-anthracenedione
• 英文别名: [9,10-Dioxo-8-(1,3-thiazole-4-carbonyloxy)anthracen-1-yl] 1,3-thiazole-4-carboxylate
• CAS: 953793-75-4
• 化学式: C₂₂H₁₀N₂O₆S₂
• 分子量: 462.463
• InChiKey: NKTGGYUXVGGEFZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  32
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  169
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  lead(II) perchlorate trihydrate 、 1,8-bis(thiazolyloxy)-9,10-anthracenedione 以 甲醇 、 氯仿 为溶剂， 生成 [(1,8-bis(thiazolyloxy)-9,10-anthracenedione)2Pb](ClO4)2
  参考文献：
  名称：

  Complexation, crystallography, and electrochemistry of new chelating nicotinyl and thiazolyl anthraquinone ligands

  摘要：

  Chelating anthraquinone ligands that contain nicotinyl and thiazolyl binding units have been synthesized. The complexation chemistry of these new ligands has also been explored using cadmium(II), lead(II), and ruthenium(II). The nicotinic substituted anthraquinone acts as a bidentate ligand, while the thiazolyl substituted anthraquinone binds in a tetradentate arrangement, not previously observed. Due to steric limitations, the number of these ligands that can coordinate to metal centers appears limited to bis-substituted products. Crystallographic data for both the free ligands and the cadmium and lead complexes are reported. Electrochemical data indicate that interaction does not take place between the intraannular carbonyl group and the neighboring metal centers within these complexes. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.05.012