3-磺酸-1,2-苯二羧酸酯铵盐(1:1) | 85959-15-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3-磺酸-1,2-苯二羧酸酯铵盐(1:1)
• 英文名称: Azanium;2-carboxy-3-sulfobenzoate
• 英文别名: azanium;2-carboxy-3-sulfobenzoate
• CAS: 85959-15-5
• 化学式: C8H9NO7S
• 分子量: 263.23
• InChiKey: JPHSPXLEYNHBAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.36
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  141
• 氢给体数：
  3
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  triammonium 4-sulfophthalate 、 3-磺酸-1,2-苯二羧酸酯铵盐(1:1) 、 尿素 生成 copper;azane;2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene-5,14,23,32-tetrasulfonic acid
  参考文献：
  名称：

  HORNA, JAROSLAV;HOLUB, MIROSLAV;MACH, KAREL

  摘要：

  DOI：

文献信息

• Primer coating composition and polymeric film coated with primer coating for silicone release applications
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0484819A2

  公开（公告）日：1992-05-13

  The present invention describes a polymeric support film coated with a primer coating composition and overcoated with a silicone release coating, thereby forming a silicone release film. Silicone release films are well known and serve as temporary supports for an adhesive or tacky surface such as for labels, pressure sensitive tape, etc. The primer coating composition, before dilution with water, comprises from about 25 to 75 % by weight of a glycidoxy silane and from about 75 to 25 % by weight of a copolyester. The copolyester comprises from about 65 to 98 mol percent isophthalic acid; from about 0 to about 30 mol percent of at least one aliphatic dicarboxylic acid; from about 2 to about 20 mol percent of at least one sulfonate group attached to a dicarboxylic nucleus; and about 100 mol percent of glycol having from about 2 to 11 carbon atoms. Typical glycidoxy silanes that can be employed in the primer coating composition include glycidoxypropyltrimethoxysilane.

  本发明描述了一种涂有底漆涂层组合物的聚合物支撑膜，该聚合物支撑膜表面涂有硅胶离型涂层，从而形成硅胶离型膜。有机硅离型膜是众所周知的，可作为粘合剂或粘性表面（如标签、压敏胶带等）的临时支撑物。底层涂料组合物在用水稀释前，由重量百分比约为 25% 至 75% 的缩水甘油醚硅烷和重量百分比约为 75% 至 25% 的共聚聚酯组成。共聚聚酯包括约 65% 至 98% 的间苯二甲酸；约 0% 至约 30% 的至少一种脂肪族二羧酸；约 2% 至约 20% 的至少一种与二羧酸核相连的磺酸基；以及约 100% 的具有约 2 至 11 个碳原子的乙二醇。可用于底层涂料组合物的典型缩水甘油硅烷包括缩水甘油丙基三甲氧基硅烷。
• A process for making and using polymeric film coated with primer coating for silicone release applications
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0541038A1

  公开（公告）日：1993-05-12

  The present invention describes a process for priming a polymeric film with a primer coating composition and overcoating with a silicone release coating. Silicone release films are well known and serve as temporary supports for an adhesive or tacky surface such as for labels, pressure sensitive tape, etc. The primer coating composition, before dilution with water, comprises from about 25 to 75% by weight of a glycidoxy silane and from about 75 to 25% by weight of a copolyester. The copolyester comprises from about 40 to 98 mol percent isophthalic acid; from about 0 to about 50 mol percent of at least one aliphatic dicarboxylic acid; from about 2 to about 20 mol percent of at least one sulfonate group attached to a dicarboxylic nucleus; and about 100 mol percent of glycol having from about 2 to 11 carbon atoms. Typical glycidoxy silanes that can be employed in the primer coating composition include glycidoxypropyltrimethoxysilane.

  本发明描述了一种用底漆涂层组合物给聚合物薄膜打底并用有机硅脱模涂层覆盖的工艺。有机硅离型膜是众所周知的，可作为粘合剂或粘性表面（如标签、压敏胶带等）的临时支撑。底层涂料组合物在用水稀释前，包括约 25% 至 75% （按重量计）的缩水甘油硅烷和约 75% 至 25% （按重量计）的共聚聚酯。共聚聚酯包括约 40% 至 98% 的间苯二甲酸；约 0% 至约 50% 的至少一种脂肪族二羧酸；约 2% 至约 20% 的至少一种与二羧酸核相连的磺酸基；以及约 100% 的具有约 2 至 11 个碳原子的乙二醇。可用于底层涂料组合物的典型缩水甘油硅烷包括缩水甘油丙基三甲氧基硅烷。
• Primer coating, polyester film having a primer coating, and a process for coating film
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0569925A2

  公开（公告）日：1993-11-18

  A polyester film coated with a novel primer coating and overcoated with one or more gelatin-aziridine coatings makes an excellent photographic film. The primer coating has about 85 - 90% by weight of a water-dispersible copolyester and about 1 - 15% by weight of an anionic surfactant. The water-dispersible copolyester contains about 80 - 98 mol % of at least one dicarboxylic acid or its ester equivalent; about 1 - 20 mol % of a sulfomonomer containing a sulfonate group attached to a dicarboxylic nucleus; and about 100 mol % of at least one glycol having 2 - 11 carbon atoms. The gelatin-aziridine coating contains about 0.5 to 100% by weight of aziridine, based on the weight of the gelatin. The gelatin-aziridine coating is sufficient to provide adhesion to or serve as a photographic gelatin coating and the aziridine being sufficient to bond the gelatin to the primed film. The gelatin-aziridine coating may constitute a single uniformly blended layer, or separate layers of gelatin and of aziridine with each layer diffused into the other. A process for producing a film useful as a photographic substrate is also disclosed.

  一种涂有新型底涂层的聚酯薄膜，外层涂有一层或多层明胶-氮丙啶涂层，可制成极好的照相胶片。底涂层含有约 85 - 90% （按重量计）的水分散性共聚聚酯和约 1 - 15% （按重量计）的阴离子表面活性剂。水分散性共聚聚酯含有约 80 - 98 mol % 的至少一种二羧酸或其酯当量；约 1 - 20 mol % 的磺酰单体，其中含有连接到二羧酸核上的磺酸基；以及约 100 mol % 的至少一种具有 2 - 11 个碳原子的乙二醇。根据明胶的重量，明胶-氮丙啶涂层含有约 0.5% 至 100% 重量的氮丙啶。明胶-氮丙啶涂层足以提供对感光明胶涂层的附着力或作为感光明胶涂层，而氮丙啶足以将明胶粘合到打底胶片上。明胶-氮丙啶涂层可以是均匀混合的单层，也可以是独立的明胶层和氮丙啶层，每一层都扩散到另一层中。此外，还公开了一种生产可用作照相底片的胶片的工艺。
• Primer coating for polymeric film
  申请人：Hoechst Diafoil GmbH

  公开号：EP0691369A1

  公开（公告）日：1996-01-10

  Described and claimed is a primer coating, and polymeric film with the primer coating making the film suitable for moisture-resistent and retort packaging applications. The primer coating comprises a shellac component and a copolyester component, both of which are water-dissolvable or dispersible. The shellac component can include modified shellac resins such as shellac varnish, shellac-lacquer, or shellac copolymers.

  描述和权利要求是一种底涂层和聚合物薄膜，底涂层使薄膜适用于防潮和蒸馏包装应用。底涂层包括一种虫胶成分和一种共聚聚酯成分，这两种成分均可在水中溶解或分散。虫胶成分可包括改性虫胶树脂，如虫胶清漆、虫胶漆或虫胶共聚物。
• Controlled release coating comprising blend of silicone and adhesion promoter
  申请人：Mitsubishi Polyester Film LLC (formely Hoechst Diafoil Co.)

  公开号：EP0920986A1

  公开（公告）日：1999-06-09

  A reclaimable release coating composition is provided which includes a blend of an adhesion promoter and a silicone release agent which may be applied from an aqueous solution, dispersion or emulsion. The components form regions of adhesion promoting sites disrupted by regions of release sites on the surface of a release backing substrate coated with the composition. The different regions are substantially homogeneously distributed across the entirety of the release surface. When used as a release coating for a backing to protect an adhesive, a controlled release force of a predictable value may be obtained by providing a known weight ratio of adhesion promoter to silicone release agent in the coating composition. A substantially linear relationship is also provided between the release force required to peel a non-silicone adhesive from the release coating surface, and the weight ratio of vinyl-functional polyorganosiloxane oil to hydrogen-functional siloxane crosslinker in the release agent, such that a consistent, uniform and repeatable release force from the surface may be obtained.

  本发明提供了一种可回收的脱模涂层组合物，该组合物包括附着力促进剂和硅氧烷脱模剂的混合物，可从水溶液、分散体或乳液中使用。在涂有该组合物的脱模衬底表面上，这些成分形成了被脱模点区域破坏的粘附促进点区域。不同的区域基本上均匀地分布在整个脱模表面上。当用作保护粘合剂的离型涂层时，通过在涂层组合物中提供已知重量比的附着力促进剂和硅氧烷离型剂，可获得可预测值的受控离型力。从脱模涂层表面剥离非硅酮粘合剂所需的脱模力与脱模剂中乙烯基官能团聚有机硅氧烷油与氢官能团硅氧烷交联剂的重量比之间也存在基本线性关系，因此可以从表面获得一致、均匀和可重复的脱模力。