N-(2-hydroxy-1-naphthylidene)-1-butylamine | 31012-22-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-(2-hydroxy-1-naphthylidene)-1-butylamine
• 英文别名: N-n-butyl-2-hydroxy-1-naphthaldimine；Butyl-<2-hydroxy-naphthyl-(1)-methylen>-amin；2-Hydroxy-1-naphthyliden-n-butylamin；2-Hydroxy-naphthaldehyd-butylimin；1-(Butyliminomethyl)naphthalen-2-ol
• CAS: 31012-22-3
• 化学式: C₁₅H₁₇NO
• 分子量: 227.306
• InChiKey: RSERDUBQTCJWPW-UHFFFAOYSA-N

物化性质

• 沸点：
  386.3±25.0 °C(Predicted)
• 密度：
  1.04±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(2-hydroxy-1-naphthylidene)-1-butylamine 、 dimethylsulfoxonium methylide 以 二甲基亚砜 为溶剂， 反应 0.5h， 以78%的产率得到Butyl-(1,2-dihydro-naphtho[2,1-b]furan-1-yl)-amine
  参考文献：
  名称：

  Nadir, Upender K; Chaurasia, Brijnath P, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1992, vol. 31, # 3, p. 189 - 190

  摘要：

  DOI：
• 作为产物：
  描述：

  正丁胺盐酸盐 、 2-羟基-1-萘甲醛 在 sodium acetate 作用下， 以 甲醇 为溶剂， 生成 N-(2-hydroxy-1-naphthylidene)-1-butylamine
  参考文献：
  名称：

  Kazitsyna,L.A. et al., Journal of general chemistry of the USSR, 1961, vol. 31, p. 286 - 294

  摘要：

  DOI：

文献信息

• The Preparation and Characterization of Dichloromanganese(IV) Schiff Base Complexes
  作者：Takayuki Matsushita、Hiroshi Kono、Toshiyuki Shono

  DOI：10.1246/bcsj.54.2646

  日期：1981.9

  oxidation state of the manganese ions in these complexes is +IV. The electronic spectra show an intense band around 16000 cm−1 which can be assigned to a charge-transfer transition. In the cyclic voltammograms, two cathodic waves are observed at half-peak potentials around +0.9 V and −0.2 V(vs. SCE); they can be assigned to the reductions of Mn(IV) to Mn(III) and of Mn(III) to Mn(II) respectiv...

  一些氯锰 (III) 席夫碱配合物与氯化氢反应生成深绿色配合物，其经验式为 MnLCl2 或 MnL'2Cl2，其中 H2L 表示四齿配体，如 N,N'-二水杨基乙二胺及其类似物，其中 HL' 表示双齿配体，如 N-丁基水杨烯胺及其类似物。这些配合物是乙腈中的非电解质。它们在室温下的磁矩在 3.9 到 4.1 BM 范围内，并且在 77 到 300 K 的温度范围内，磁化率服从居里-魏斯定律，θ 值很小，表明锰离子在这些复合物是+IV。电子光谱在 16000 cm-1 附近显示出一个强带，可以将其指定为电荷转移跃迁。在循环伏安图中，在 +0.9 V 和 -0.2 V（vs. SCE）附近的半峰电位处观察到两个阴极波；它们可以分别归因于 Mn(IV) 到 Mn(III) 和 Mn(III) 到 Mn(II) 的还原……
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: U: SVol.E2, 1.7.5, page 60 - 104
  作者：

  DOI：——

  日期：——
• Structures and properties of di-μ-oxo dimanganese(IV) complexes with bidentate Schiff bases, N-alkyl-substituted-salicylideneamine
  作者：Hitoshi Torayama、Hideyuki Asada、Manabu Fujiwara、Takayuki Matsushita

  DOI：10.1016/s0277-5387(98)00144-2

  日期：1998.11

  Novel di-mu-oxo dimanganese(IV) complexes, [Mn-IV(N-R-X-sal)(2)(mu-O)](2), with bidentate Schiff base ligands, N-alkyl-substituted-salicylideneamine, N-R-X-salH [R= CH3(Me), C2H5 (Et), n-C3H, (Pr), n-C4H9 (Bu), n-C6H13 (Hx), n-C8H17 (Oct), II-C10H21 (Dec), n-C12H25 (Dod), or n-C18H37 (Octd) and X = H or 5,6-benzo]: have been prepared by their reaction with potassium permanganate (KMnO4) in MeCN, while stirring at room temperature. These complexes were characterized by spectroscopy, magnetic susceptibility, thermal analysis and X-ray crystallography. The structures consist of a Mn-2(IV)(mu-O)(2) core with a Mn-Mn separation of 2.731 (4) Angstrom for [Mn-IV(N-Me-sal)(2)(mu-O)](2), 1, 2.769(2) Angstrom for [Mn-2(IV)(N-Et-sal)(2)(mu-O)](2), 2, 2.780(2) Angstrom for [(Mn-IV-Hx-sal)(2)(mu-O)](2), 5, 2.780(2)Angstrom for [Mn-IV(N-Dec-sal)(2)(mu-O)](2), 7, and 2.756(3) Angstrom for [Mn-IV(N-Me-5,6-benzo-sal)(2)(mu-O)](2), 10. The complex 1 is the first di-mu-oxo dimanganese(IV) complex having asymmetrical form in which two manganese ions adopt different configurations each other. Moreover, the complexes 5 and 7 are found to exhibit the longest one among all of the Mn-Mn separation observed for the structurally characterized Mn-2(mu-O)(2) complexes prior to this work. The antiferromagnetic exchange interaction has been found to be J= -83 and -188 cm(-1) for 1 and 7, respectively. (C) 1998 Elsevier Science Ltd. All rights reserved.
• Schiff base complexes of dioxouranium(VI)-(IV) dioxouranium(VI) chloride complexes with monobasic bidentate Schiff bases
  作者：R.G. Vijay、J.P. Tandon

  DOI：10.1016/0022-1902(77)80360-6

  日期：1977.1
• Yamada, S.; Takeuchi, A., Bulletin of the Chemical Society of Japan, 1969, vol. 42, p. 2549 - 2551
  作者：Yamada, S.、Takeuchi, A.

  DOI：——

  日期：——