6,13-dihydro-6,13-(2,3,4,5-tetrachloro-2,4-cyclohexadieno)pentacene | 239089-14-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 6,13-dihydro-6,13-(2,3,4,5-tetrachloro-2,4-cyclohexadieno)pentacene
• 英文别名: 24,25,26,27-Tetrachloroheptacyclo[10.10.6.02,11.04,9.013,22.015,20.023,28]octacosa-2,4,6,8,10,13,15,17,19,21,24,26-dodecaene
• CAS: 239089-14-6
• 化学式: C₂₈H₁₆Cl₄
• 分子量: 494.247
• InChiKey: VLWUBDZXWPZATM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  32
• 可旋转键数：
  0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  24,25,26,27-Tetrachloro-29,29-dimethoxyoctacyclo[10.10.6.124,27.02,11.04,9.013,22.015,20.023,28]nonacosa-2,4,6,8,10,13,15,17,19,21,25-undecaene 在 硫酸 、 水 作用下， 以 正庚烷 、 甲苯 为溶剂， 反应 72.0h， 以74%的产率得到6,13-dihydro-6,13-(2,3,4,5-tetrachloro-2,4-cyclohexadieno)pentacene
  参考文献：
  名称：

  [EN] METHOD OF PREPARATION OF A PRECURSOR OLIGOCENE
  [FR] PROCEDE DE PREPARATION D'UN OLIGOCENE PRECURSEUR

  摘要：

  一种前体寡聚物，特别是五环芴的合成是一个两步过程。在第一步中，将α，β-二氢-α，β-乙烯基寡聚物与1,1-二烷氧基环戊二烯的Diels-Alder加合物形成。在第二步中，将这种Diels-Alder加合物转化为前体寡聚物，首先形成相应的酮化合物，然后可能被消除。所得的前体寡聚物可以通过热处理转化为寡聚物，特别是在将其溶液涂覆在基底上后。它适用于作为薄膜晶体管中的半导体材料。公式（I）。

  公开号：

  WO2004083160A1

文献信息

• PHOTOELECTRIC CONVERSION DEVICE AND SOLAR CELL USING THE SAME
  申请人：AKIYAMA Seiji

  公开号：US20120211082A1

  公开（公告）日：2012-08-23

  There is provides a photoelectric conversion device material which can be used as an electrode buffer material for a solar cell or the like and can improve durability while maintaining the interaction with an electrode and mobility; a photoelectric conversion device using the photoelectric conversion device material; and a solar cell using the photoelectric conversion device. A photoelectric conversion device containing a buffer layer and an active layer, wherein the buffer layer contains a compound represented by the following general formula (I), the active layer contains an n-type semiconductor, and the n-type semiconductor is a compound having a solubility in toluene of 0.5% by weight or more at 25° C. and having an electron mobility of 1.0×10 −6 cm 2 /Vs or more.

  提供了一种光电转换器件材料，可用作太阳能电池或类似器件的电极缓冲材料，可以提高耐久性，同时保持与电极的相互作用和移动性；使用该光电转换器件材料的光电转换器件；以及使用该光电转换器件的太阳能电池。光电转换器件包含缓冲层和活性层，其中缓冲层包含由下列通式（I）表示的化合物，活性层包含n型半导体，且该n型半导体在25℃时在甲苯中的溶解度为0.5%或更高，并具有1.0×10−6cm2/Vs或更高的电子迁移率。
• PROCESS FOR PRODUCING ORGANIC PHOTO-ELECTRIC CONVERTING ELEMENT AND ORGANIC PHOTO-ELECTRIC CONVERTING ELEMENT
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2023419A1

  公开（公告）日：2009-02-11

  The objects are to provide a method for producing a durable organic photoelectric conversion device by a coating process or to produce an organic photoelectric conversion device superior in photoelectric conversion characteristics to the conventional devices. In the production method for an organic photoelectric conversion device including a substrate, a pair of electrodes which are formed on the substrate and at least one of which is transparent, and an active layer formed between the pair of electrodes, the active layer is formed by coating; and the active layer contains a pigment

  目的是提供一种通过涂层工艺生产耐用有机光电转换装置的方法，或生产一种光电转换特性优于传统装置的有机光电转换装置。在有机光电转换器件的生产方法中，该器件包括基板、形成在基板上的一对电极（其中至少有一个是透明的）以及形成在这对电极之间的活性层，活性层是通过涂层形成的；并且活性层含有颜料
• METHOD FOR PRODUCING ORGANIC PHOTOELECTRIC CONVERSION DEVICE AND ORGANIC PHOTOELECTRIC CONVERSION DEVICE
  申请人：Aramaki Shinji

  公开号：US20090308458A1

  公开（公告）日：2009-12-17

  The objects are to provide a method for producing a durable organic photoelectric conversion device by a coating process or to produce an organic photoelectric conversion device superior in photoelectric conversion characteristics to the conventional devices. In the production method for an organic photoelectric conversion device including a substrate, a pair of electrodes which are formed on the substrate and at least one of which is transparent, and an active layer formed between the pair of electrodes, the active layer is formed by coating; and the active layer contains a pigment
• US7402707B2
  申请人：——

  公开号：US7402707B2

  公开（公告）日：2008-07-22
• US9136489B2
  申请人：——

  公开号：US9136489B2

  公开（公告）日：2015-09-15