[(PdI(4,4'-di-tert-butyl-2,2'-bipyridine))3(μ-C6Me3-1,3,5)] | 378762-53-9

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: [(PdI(4,4'-di-tert-butyl-2,2'-bipyridine))3(μ-C6Me3-1,3,5)]
• 英文别名: [(PdI(4,4'-di-tert-butyl-2,2'-bipyridine))3(μ3-C6Me3)]
• CAS: 378762-53-9
• 化学式: C₆₃H₈₁I₃N₆Pd₃
• 分子量: 1622.35
• InChiKey: UXZONRNJGFSBSZ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(PdI(4,4'-di-tert-butyl-2,2'-bipyridine))3(μ-C6Me3-1,3,5)] 以 氘代甲苯 为溶剂， 生成 [(PdI(4,4'-di-tert-butyl-2,2'-bipyridine))2(μ-C6HMe3-1,3,5)]
  参考文献：
  名称：

  Synthesis of Pd₃Tl and Pd₆Tl₂Complexes Based on a Trinuclear Aryl–Palladium(II) Complex Acting as a Metallaligand Toward Thallium(I) Through Tl–Arene and Tl–I Bonds

  摘要：

  The metallaligand [(PdIL2)(3)(C6Me3-1,3,5)] (L-2 = 4,4'-di-tert-butyl-2-2'-bipyridine = tbbpy) reacts with TIOTf to afford the complex [{(PdIL2)(3)C6Me3-1,3,5}Tl]OTf, which exists in the solid state as a 2:1 mixture of monomer and dimer, both showing Tl(I)-I and Tl(I)-eta(6)-mesitylene bonds. In solution, only the monomer is observed. Heating of toluene solutions of [(PdIL2)(3)(C6Me3-1,3,5)] affords the dinuclear complex [(PdIL2)(2)(C6HMe3-1,3,5)].

  DOI：

  10.1021/ic2007793
• 作为产物：
  描述：

  [((PdI(4,4'-di-tert-butyl-2,2'-bipyridine)3(C6Me3-1,3,5))Tl]OTf 在 NaI 作用下， 以 not given 为溶剂， 生成 [(PdI(4,4'-di-tert-butyl-2,2'-bipyridine))3(μ-C6Me3-1,3,5)]
  参考文献：
  名称：

  Synthesis of Pd₃Tl and Pd₆Tl₂Complexes Based on a Trinuclear Aryl–Palladium(II) Complex Acting as a Metallaligand Toward Thallium(I) Through Tl–Arene and Tl–I Bonds

  摘要：

  The metallaligand [(PdIL2)(3)(C6Me3-1,3,5)] (L-2 = 4,4'-di-tert-butyl-2-2'-bipyridine = tbbpy) reacts with TIOTf to afford the complex [{(PdIL2)(3)C6Me3-1,3,5}Tl]OTf, which exists in the solid state as a 2:1 mixture of monomer and dimer, both showing Tl(I)-I and Tl(I)-eta(6)-mesitylene bonds. In solution, only the monomer is observed. Heating of toluene solutions of [(PdIL2)(3)(C6Me3-1,3,5)] affords the dinuclear complex [(PdIL2)(2)(C6HMe3-1,3,5)].

  DOI：

  10.1021/ic2007793

文献信息

• Polymetalated Aromatic Compounds. 1. Synthesis of Mono-, Di-, and Tripalladated Mesitylene Derivatives
  作者：José Vicente、Mykhaylo Lyakhovych、Delia Bautista、Peter G. Jones

  DOI：10.1021/om0105472

  日期：2001.10.1

  5-triiodomesitylene (C6Me3I3) with a mixture of [Pd(dba)2] and PR3 leads to the mononuclear complexes trans-[Pd(C6Me3I2)I(PR3)2] (R = Ph (1), R3 = Me2Ph (2)) or the dinuclear complex [trans-PdI(PMe2Ph)2}2(μ2-C6Me3I)] (3), depending on the nature of the phosphine, the temperature, and the molar ratio of the reagents. All attempts to prepare trinuclear complexes, using this method of synthesis, were unsuccessful

  1,3,5-三碘杂环丁烯（C 6 Me 3 I 3）与[Pd（DBA）2 ]和PR 3的混合物的反应导致单核络合物反式-[Pd（C 6 Me 3 I 2）I （PR 3）2 ]（R =苯基（1）中，R 3 =我2 Ph（上2））或双核配合物[反式-PdI（PME 2 PH）2 } 2（μ 2 -C 6我3我）]（3），取决于膦的性质，温度和试剂的摩尔比。使用这种合成方法制备三核复合物的所有尝试均未成功。然而，C的加入6我3我3到的混合物[加入Pd（DBA）2 ]和L 2给出了在室温下[（PDIL 2）3（μ 3 -C 6我3）]（L 2 = 2，即使使用亚化学计量的Pd，2'-联吡啶（bpy）（4），4,4'-二叔丁基-2,2'-联吡啶（tbbpy）（5））。复杂5不与反应PPH 3或PME 2 PH，但它确实用PMe反应3开始，得到[反式- PDI（PME 3）2 } 3（μ 3 -C