[Cu(bzac)(2,4,6-Me3C6H2-BIAN)]ClO4 | 697740-88-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [Cu(bzac)(2,4,6-Me3C6H2-BIAN)]ClO4
• 英文别名: [Cu(benzoylacetonate)(bis[N-(2,4,6-trimethylphenyl)imino]acenaphthene)]ClO4
• CAS: 697740-88-8
• 化学式: C₄₀H₃₇CuN₂O₂*ClO₄
• 分子量: 740.743
• InChiKey: DQIHUVBLPMIXAB-NFSZIFMVSA-M

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 bis[N-(2,4,6-trimethylphenyl)imino]acenaphthene 、 1-苯基-1,3-丁二酮 以 乙醇 为溶剂， 以78%的产率得到[Cu(bzac)(2,4,6-Me3C6H2-BIAN)]ClO4
  参考文献：
  名称：

  Synthesis, structural and solvent influence studies on solvatochromic mixed-ligand copper(II) complexes with the rigid nitrogen ligand: bis[N-(2,4,6-trimethylphenyl)imino]acenaphthene

  摘要：

  Three mixed-ligand copper (11) complexes containing the rigid bidentate nitrogen ligand bis[N-(2,4,6-trimethylphenyl)imino] acenaphthene (abbr. 2,4,6-Me3C6H2-BIAN) and beta-diketonate (dike) ligands are reported and characterized. These complexes namely, [Cu (dike)(2,4,6-Me3C6H2-BIAN)] ClO4 { where dike= acac (acetylacetonate), bzac (benzoylacetonate) or (dibm) dibenzoylmethanate} have been synthesized and characterized by elemental analysis, spectroscopic, magnetic and molar conductance measurements. In addition to their high solubility in various organic solvents, these three complexes show a color change on going from one solvent to another, that is, strong solvatochromism of their solutions. The observed solvatochromism is mainly due to the solute-solvent interaction between the chelate cation and the solvent molecules. Reported also are the X-ray crystal structures of the free 2,4,6-Me3C6H2-BIAN ligand and the [Cu(acac)(2,4,6-Me3C6H2-BIAN)]ClO4 complex. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2004.01.040