[Pt(2-phenylpyridine)(1,4,7-trithiacyclononane)](PF6) | 870681-15-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Pt(2-phenylpyridine)(1,4,7-trithiacyclononane)](PF6)
• 英文别名: 2-phenylpyridine;platinum(2+);1,4,7-trithionane;hexafluorophosphate
• CAS: 870681-15-5
• 化学式: C₁₇H₂₀NPtS₃*F₆P
• 分子量: 674.595
• InChiKey: BJEKYFNIHXKSIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.13
• 重原子数：
  29
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  88.8
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  1,4,7-三硫环壬烷 、 [{Pt(ppy)Cl}₂] 以 乙腈 为溶剂， 生成 [Pt(2-phenylpyridine)(1,4,7-trithiacyclononane)](PF6)
  参考文献：
  名称：

  Cationic Five-Coordinate Pt^II Complexes as Donors in the Formation of Pt→Ag Dative Bonds

  摘要：

  A unique trinuclear cluster containing two short Pt -> Ag dative bonds was prepared and characterized crystallographically. Two monocationic orthometalated Pt-II complexes containing 2-phenylpyridine and the tridentate ligand 9S3 (1,4,7-trithiacyclononane) exhibit axial sulfur interactions with Pt as well as short dative bonds. The Pt -> Ag dative bonding results in a dramatic shortening of the axial Pt-S distance in each Pt complex cation, relative to the mononuclear Pt complex. Evidence for Pt-Ag interactions in solution is also presented.

  DOI：

  10.1021/ic0511874