[Ge((C6H4)OCHN2CO(C6H4(3-NO2)))2] | 412351-57-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ge((C6H4)OCHN2CO(C6H4(3-NO2)))2]
• CAS: 412351-57-6
• 化学式: C₂₈H₁₈GeN₆O₈
• 分子量: 639.076
• InChiKey: IVAKCSSEJYCWKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四氯化锗 、 salicylidene-3-nitrobenzoyl hydrazide 以 甲醇 为溶剂， 以80%的产率得到[Ge((C6H4)OCHN2CO(C6H4(3-NO2)))2]
  参考文献：
  名称：

  摘要：

  New germanium(IV) complexes with N-[X-benzoyl]hydrazones of salicylaldehyde (X-H2L, where X = 2-, 3-, and 4-NO2; H2L = C6H4-CO-NH-NCH-C6H4OH) with the compositions [Ge(2-NO2-L)(2)], [Ge(3-NO2-L)(2)], and [Ge(4-NO2-L)(2)] were synthesized. The data of IR, UV, and H-1, C-13 NMR spectroscopy showed that the complexes had an octahedral structure and ligand coordination through the nitrogen atom of the azomethine group and two oxygen atoms of the doubly deprotonated form of the ligand. The thermal stability of the complexes was studied. The specific features of the mass spectrometric behavior of the substances in the gas phase under electron impact were considered.

  DOI：

  10.1023/a:1013755502556