[(2,4,6-Me3C6H2)N(SiMe3)SiO(OAl-(i)Bu2)(OAl-(i)Bu)]2 | 173916-56-8

• 英文名称: [(2,4,6-Me3C6H2)N(SiMe3)SiO(OAl-(i)Bu2)(OAl-(i)Bu)]2
• CAS: 173916-56-8
• 化学式: C₄₈H₉₄Al₄N₂O₆Si₄
• 分子量: 1015.55
• InChiKey: YCIRPOGTECZDAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,4-二氧六环 、 二异丁基氢化铝 、 (2,4,6-Me3C6H2)N(SiMe3)(Si(OH)3) 以 1,4-二氧六环 、 正己烷 为溶剂， 以99%的产率得到[(2,4,6-Me3C6H2)N(SiMe3)SiO(OAl-(i)Bu2)(OAl-(i)Bu)]2
  参考文献：
  名称：

  Cyclic and Polyhedral Aluminosiloxanes with Al₂Si₂O₄, Al₄Si₂O₆, and Al₄Si₄O₁₂ Frameworks:  X-ray Crystal Structures of [(2,4,6-Me₃C₆H₂)N(SiMe₃)Si(OAlBu-i)(OAl(Bu-i)₂)O]₂ and [(2,6-Me₂C₆H₃)N(SiMe₃)SiO₃Al·C₄H₈O₂]₄

  摘要：

  Reactions of (silylamino)silanetriols RN(SiMe(3))Si(OH)(3) (R = 2,4,6-Me(3)C(6)H(2) (1) and 2,6-Me(2)C(6)H(3) (2)) with i-Bu(2)AlH in 1:1 molar ratio at -78 degrees C afford aluminosiloxanes [RN(SiMe(3))Si(OH)O(OAlBu-i . dioxane)](2) (R = 2,4,6-Me(3)C(6)H(2) (3) and 2,6-Me(2)C(6)H(3) (4)) and [RN(SiMe(3))Si(OAlBu-i)(OAl(Bu-i)(2))O](2) (R = 2,4,6-Me(3)C(6)H(2) (5) and 2,6-Me(2)C(6)H(3) (6)), respectively. While 3 and 4 are eight-membered Al2Si2O4 cyclic compounds, 5 and 6 are drum-shaped aluminosiloxanes with an Al4Si2O6 core. When the same reactions were carried out in 1:2 molar ratio of the reactants at -78 degrees C, only the drum-shaped polyhedral compounds 5 and 6 are isolated. The reactions between the silanetriols and i-Bu(2)AlH in 1:1 molar ratio at 65 degrees C proceed quantitatively to yield the cubic aluminosiloxanes [RN(SiMe(3))SiO3Al . dioxane](4) (R = 2,4,6-Me(3)C(6)H(2) (7) and 2,6-Me(2)C(6)H(3) (8)) with an Al4Si4O12 framework. The X-ray crystal structures of 5 and 8 have been determined.

  DOI：

  10.1021/om950685p