[(1,1'-bis(diphenylselenophosphoryl)ferrocene)Ag]ClO4*CH2Cl2 complex | 261503-08-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(1,1'-bis(diphenylselenophosphoryl)ferrocene)Ag]ClO4*CH2Cl2 complex
• 英文别名: silver;cyclopenta-2,4-dien-1-yl-diphenyl-selanylidene-λ5-phosphane;dichloromethane;iron(2+);perchlorate
• CAS: 261503-08-6
• 化学式: CH₂Cl₂*C₃₄H₂₈AgFeP₂Se₂*ClO₄
• 分子量: 1004.56
• InChiKey: JESDIRGOABKPCI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,1'-bis(diphenylselenophosphoryl)ferrocene 、 AgClO4*4acetonitrile 、 二氯甲烷 以 二氯甲烷 为溶剂， 生成 [(1,1'-bis(diphenylselenophosphoryl)ferrocene)Ag]ClO4*CH2Cl2 complex
  参考文献：
  名称：

  trans-Chelating ligating ability of 1,1′-bis(diphenylselenophosphoryl)ferrocene (dpspf) towards silver(I). Crystal structure of [Ag(dpspf)]ClO4

  摘要：

  The ligand 1,1'-bis(diphenylselenophosphoryl)ferrocene Fe[eta(5)-C5H4P(Se)Ph-2](2) (dpspf), reacted readily with [Ag(MeCN)(4)]ClO4 in CH2Cl2 to quantitatively give the monomeric two-coordinated complex [Ag(dpspf)]ClO4. The solution behavior of the complex has been probed by variable-concentration and/or -temperature multinuclear NMR spectroscopy (H-1, C-13, P-31 and Se-77), which revealed extreme lability. Single-crystal X-ray structural analysis shows that the complex (orthorhombic, Pna2(1), a = 26.34(1), b = 12.363(6), c = 11.209(6) Angstrom, Z = 4) exists as mononuclear species in an almost linear two-coordination environment around the silver atom with an Se(1)-Ag-Se(2) angle of 176.5(1)degrees. The Ag-Se bond distances (2.456(4) and 2.449(3) Angstrom) and the Ag-Se-P angles (98.1(2) and 102.6(2)degrees) point towards a substantially sp(3) hybridization of the selenium donor atoms. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00439-9