(N-tert-butylbenzenesulfenamido)chloro(η(4)-1,2,3,4-tetramethylfulvene)ruthenium(II) | 185259-05-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: (N-tert-butylbenzenesulfenamido)chloro(η(4)-1,2,3,4-tetramethylfulvene)ruthenium(II)
• 英文别名: tert-butyl(phenylsulfanyl)azanide;chlororuthenium(1+);1,2,3,4-tetramethyl-5-methylidenecyclopenta-1,3-diene
• CAS: 185259-05-6
• 化学式: C₂₀H₂₈ClNRuS
• 分子量: 451.038
• InChiKey: MJRXPQJRKDADNI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  7.78
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  Li(ButNSPh) 、 以 甲苯 为溶剂， 以10%的产率得到(N-tert-butylbenzenesulfenamido)chloro(η(4)-1,2,3,4-tetramethylfulvene)ruthenium(II)
  参考文献：
  名称：

  Synthesis and crystal structures of η²-sulfenamido complexes of ruthenium and nickel, and of chromium imido and cobalt iminophosphorane complexes via sulfenamido rearrangement

  摘要：

  The interaction of [Ru(eta-C(5)Me(5))Cl-2](2) with Li(Bu(t)NSPh), gave two products, Ru(eta(4)-C(5)Me(4)CH(2))(eta(2)-Bu(t)NSPh)Cl 1 and the dimer Cl(eta-C(5)Me(5))Ru(mu-NBu(t))(mu-SPh)Ru(eta-C(5)Me(5)) 2; the former is best described as a eta(4)-tetramethylfulvene ruthenium(II) complex, while in the latter the bridging tert-butylimido and benzene-thiolato groups were formed by S-N cleavage of sulfenamido species. A similar cleavage resulted in the formation of Cr-V(eta-C(5)Me(5))(NBu(t))(SPh)(2) 3, in the interaction of Li(Bu(t)NSPh) with [Cr(eta-C(5)Me(5))Br-2](2). Interaction of CoCl2(PMe(3))(3) with Li(p-MeC(6)H(4)NSPh) gave the iminophosphorane complex Co(p-MeC(6)H(4)NPMe(3))(2)(SPh)(2) 4. Interaction of NiCl2(PMe(3))(2) with Li(Bu(t)NSPh) gave Ni(eta(2)-Bu(t)NSPh)(2)(PMe(3)) 5. The structures of compounds 1-5 have been confirmed by X-ray crystallography.

  DOI：

  10.1039/dt9960004063