Ru(2,3,7,8,12,13,17,18-octaethylporphyrinate)(NO)(triflate) | 235421-26-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Ru(2,3,7,8,12,13,17,18-octaethylporphyrinate)(NO)(triflate)
• CAS: 235421-26-8
• 化学式: C₃₇H₄₄F₃N₅O₄RuS
• 分子量: 812.919
• InChiKey: DLBTWXUZOYHDQR-SBYLDBAISA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ru(2,3,7,8,12,13,17,18-octaethylporphyrinate)(NO)(triflate) 、 以 二氯甲烷 为溶剂， 以71%的产率得到(2,3,7,8,12,13,17,18-octaethylporphyrinate)(NO)RuNRe(diethyldithiocarbamate)2(triflate)
  参考文献：
  名称：

  Heterobimetallic nitrido-bridged Ru(II)NOs(VIII) and Ru(II)NOs(VI) complexes containing ruthenium porphyrins

  摘要：

  Treatment of Ru(por)(NO)(OTf) (por=dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin H-2(OEP) or 5,10,15,20-tetra(p-tolyl)porphyrin H-2(TTP), OTf=triflate) with [(NBu4)-Bu-n][OsO3N] afforded the nitrido-bridged Ru(II)-Os(VIII) complexes [(por)(NO)RuNOsO3] (por=OEP (3) or TTP (4)). The structure of 3 has been established by X-ray crystallography. The Ru-N(O), Ru-N(Os and Os-N distances in 3 are 1.83(2, 2.03(1) and 1.79(1) Angstrom, respectively; the Ru-N-O and Ru-N-Os angles are 153(1) and 138.4(8)degrees, respectively. Reaction of Ru(por)(NO)(OTf) with [(NBu4)-Bu-n]OsNL2] (H2L = 3,4-toluenedithiol) gave the nitrido-bridged Ru(II)-Os(VI) complexes (por)(NO)RuNOsL2 (por = OEP (5), TTP (6)). Treatment of Ru(OEP)(NO)(OTf) with ReN(Et(2)dtc)(2) (Et(2)dtc = N,N-diethyldithiocarbamate) afforded the Ru(IT)-Re(V) complex (OEP)(NO)RuNRe(Et(2)dtc)(2)(OTf) (7). Complexes 3 and 4 exhibit porphyrin-centered oxidation along with Os(VIII)-Os(VIT) and Ru(II)-Ru(I) reductions. Complexes 5 and 6 exhibit Os(VII)-Os(VI) and porphyrin ring oxidation along with Ru(II)-Ru(I) reduction. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00096-1
• 作为产物：
  描述：

  Ru(2,3,7,8,12,13,17,18-octaethylporphyrinate)(NO)Cl 、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 生成 Ru(2,3,7,8,12,13,17,18-octaethylporphyrinate)(NO)(triflate)
  参考文献：
  名称：

  Heterobimetallic nitrido-bridged Ru(II)NOs(VIII) and Ru(II)NOs(VI) complexes containing ruthenium porphyrins

  摘要：

  Treatment of Ru(por)(NO)(OTf) (por=dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin H-2(OEP) or 5,10,15,20-tetra(p-tolyl)porphyrin H-2(TTP), OTf=triflate) with [(NBu4)-Bu-n][OsO3N] afforded the nitrido-bridged Ru(II)-Os(VIII) complexes [(por)(NO)RuNOsO3] (por=OEP (3) or TTP (4)). The structure of 3 has been established by X-ray crystallography. The Ru-N(O), Ru-N(Os and Os-N distances in 3 are 1.83(2, 2.03(1) and 1.79(1) Angstrom, respectively; the Ru-N-O and Ru-N-Os angles are 153(1) and 138.4(8)degrees, respectively. Reaction of Ru(por)(NO)(OTf) with [(NBu4)-Bu-n]OsNL2] (H2L = 3,4-toluenedithiol) gave the nitrido-bridged Ru(II)-Os(VI) complexes (por)(NO)RuNOsL2 (por = OEP (5), TTP (6)). Treatment of Ru(OEP)(NO)(OTf) with ReN(Et(2)dtc)(2) (Et(2)dtc = N,N-diethyldithiocarbamate) afforded the Ru(IT)-Re(V) complex (OEP)(NO)RuNRe(Et(2)dtc)(2)(OTf) (7). Complexes 3 and 4 exhibit porphyrin-centered oxidation along with Os(VIII)-Os(VIT) and Ru(II)-Ru(I) reductions. Complexes 5 and 6 exhibit Os(VII)-Os(VI) and porphyrin ring oxidation along with Ru(II)-Ru(I) reduction. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00096-1