bis(salicylidene(4-dimethylamino)aniline)zinc(II) | 874183-91-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(salicylidene(4-dimethylamino)aniline)zinc(II)
• 英文别名: [Zn(sada)2]；[Zn(salicylidene(4-dimethylamino)aniline(-H))2]
• CAS: 874183-91-2
• 化学式: C₃₀H₃₀N₄O₂Zn
• 分子量: 543.984
• InChiKey: HLFXWAWPLOMRGR-NMOKDUCBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (6E)-6-[[4-(dimethylamino)anilino]methylidene]cyclohexa-2,4-dien-1-one 、 zinc(II) chloride 在 piperidine 作用下， 以 乙醇 为溶剂， 以86%的产率得到bis(salicylidene(4-dimethylamino)aniline)zinc(II)
  参考文献：
  名称：

  An azomethin-zinc complex for organic electroluminescence: Crystal structure, thermal stability and optoelectronic properties

  摘要：

  An azomethin-zinc complex, bis[salicylidene(4-dimethylamino)aniline]zinc(II) (Zn(sada)(2)) was synthesized and structurally characterized by single-crystal X-ray crystallography. Crystal data for Zn(C15H15N2O)(2) was determined as follows: space group, triclinic, P (l) over bar; a = 10.2791(9) angstrom, b = 16.5008(14) angstrom, c = 17.5984(15) angstrom, alpha = 114.830(2)degrees, beta = 96.579(2)degrees, gamma = 97.674(2)degrees, Z = 4. Through thermal analysis characterization and FT-IR spectra, this complex was proved to have good thermal stability. The vapor-deposited films exhibited uniform and environment-stable morphology. The light emission and charge transporting performance of Zn(sada)2 in organic light emitting diodes (OLEDs) were investigated preliminarily, and the results indicated the superior electron transporting property of this complex. Compared with the typical bilayer device of NN'-diphenyl-N,N'-bis(1-naptithyl)-benzidine (NPB)/tris-(8-hydroxyquinoline)aluminum (Alq(3)), the device with Zn(sada)(2) as the electron transporting layer exhibited a much lower turn-on voltage of 2.5 V (it is usually 3.5 V for an NPB/Alq(3) device). (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.08.018