B-HH-B | 1160067-02-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: B-HH-B
• 英文别名: 2,2'-(4,4'-Dihexyl-2,2'-bithiophene-5,5'-diyl)bis[5,5-difluoro-4H-cyclopenta[b]thiophene-4,6(5H)-dione]；2-[5-[5-(5,5-difluoro-4,6-dioxocyclopenta[b]thiophen-2-yl)-4-hexylthiophen-2-yl]-3-hexylthiophen-2-yl]-5,5-difluorocyclopenta[b]thiophene-4,6-dione
• CAS: 1160067-02-6
• 化学式: C₃₄H₃₀F₄O₄S₄
• 分子量: 706.867
• InChiKey: ADQFUAGPEUCUIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.7
• 重原子数：
  46
• 可旋转键数：
  13
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  181
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  在 硫酸 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以26 mg的产率得到B-HH-B
  参考文献：
  名称：

  Electronegative Oligothiophenes Having Difluorodioxocyclopentene-annelated Thiophenes as Solution-processable n-Type OFET Materials

  摘要：

  我们合成了含有二氟二氧环戊烯-沟道化噻吩的可溶液加工的负电性低聚噻吩。通过吸收光谱和电化学测量研究了这些低聚物的电子特性。通过旋涂法制造的薄膜显示出典型的 n 沟道 OFET 行为。

  DOI：

  10.1246/cl.2009.460

文献信息

• Nitrogen-containing fused-ring compound, polymer comprising a nitrogen-containing fused-ring repeating unit, organic thin film, and organic thin film element
  申请人：SUMITOMO CHEMICAL CO., LTD.

  公开号：EP2520572A1

  公开（公告）日：2012-11-07

  The present invention provides nitrogen-containing fused-ring compounds represented by the following formula (α-I): in formula (α-I), R21 and R22 each independently represent a hydrogen atom, a halogen atom or an optionally substituted monovalent group, and Z21 and Z22 each independently represent any one of the groups represented by the following formulas (α-i)-(α-ix); wherein R23, R24, R25 and R26 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and R23 and R24 may bond together to form a ring, the left side and the right side of the group represented by formula (α-viii) may be interchanged.

  本发明提供了由下式（α-I）表示的含氮熔环化合物： 式(α-I)中，R21和R22各自独立地代表氢原子、卤素原子或任选取代的一价基团，Z21和Z22各自独立地代表下式(α-i)-(α-ix)所代表的基团中的任一个； 其中 R23、R24、R25 和 R26 各自独立地代表氢原子、卤素原子或单价基团，且 R23 和 R24 可键合在一起形成环，式 (α-viii) 所代表基团的左侧和右侧可互换。
• EP2223918
  申请人：——

  公开号：——

  公开（公告）日：——
• CONJUGATED COMPOUND, NITROGENATED CONDENSED-RING COMPOUND, NITROGENATED CONDENSED-RING POLYMER, ORGANIC THIN FILM, AND ORGANIC THIN FILM ELEMENT
  申请人：Aso Yoshio

  公开号：US20100301314A1

  公开（公告）日：2010-12-02

  According to the first invention group there are provided conjugated compounds having two or more groups represented by the following formula (I) or the following formula (II): wherein one of Ar and Ar′ represents a C6 or greater divalent aromatic hydrocarbon group and the other represents a C4 or greater divalent heterocyclic group, wherein the groups each may have a substituent, with the proviso that the groups as a whole contain no fluorine atoms, R 1 and R 2 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and Ar″ represents a trivalent aromatic hydrocarbon or trivalent heterocyclic group; when the conjugated compound has two or more groups represented by formula (I), the portion excluding these groups contain no fluorine atoms. According to the second group of the present invention there are provided nitrogen-containing fused-ring compounds represented by the following formula (α-I): in formula (α-I), R 21 and R 22 each independently represent a hydrogen atom, a halogen atom or an optionally substituted monovalent group, and Z 21 and Z 22 each independently represent any one of the groups represented by the following formulas (α-i)-(α-ix); wherein R 23 , R 24 , R 25 and R 26 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and R 23 and R 24 may bond together to form a ring, the left side and the right side of the group represented by formula (α-viii) may be interchanged.
• CONJUGATED COMPOUND, AND ORGANIC THIN FILM AND ORGANIC THIN FILM ELEMENT EACH COMPRISING SAME
  申请人：Ie Yutaka

  公开号：US20120049174A1

  公开（公告）日：2012-03-01

  A conjugated compound having a group represented by formula (I) and/or formula (II). [In the formulas, Ar represents an optionally substituted trivalent aromatic hydrocarbon or optionally substituted trivalent heterocyclic group, and A represents hydrogen, a halogen atom or a monovalent group. When multiple A groups are present they may be the same or different, and at least one A represents an electron-withdrawing group. Ar′ represents an optionally substituted C6 or greater divalent aromatic hydrocarbon or optionally substituted C4 or greater divalent heterocyclic group, and R 1 and R 2 are the same or different and each represents hydrogen, a halogen atom or a monovalent group, while A′ represents hydrogen, a halogen atom or a monovalent group. When multiple A′ groups are present they may be the same or different, and at least one A′ represents an electron-withdrawing group.]
• US8378338B2
  申请人：——

  公开号：US8378338B2

  公开（公告）日：2013-02-19