bpyH{RuCl4(bpy)} | 17099-67-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: bpyH{RuCl4(bpy)}
• CAS: 17099-67-1
• 化学式: C₁₀H₈Cl₄N₂Ru*C₁₀H₈N₂*H*H₂O
• 分子量: 574.279
• InChiKey: GNOHAEVYHIKLRQ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bpyH{RuCl4(bpy)} 在 Cl₂ 、 ethanol 作用下， 以 盐酸 、 水 为溶剂， 生成 {RuCl2(aca)(bpy)}
  参考文献：
  名称：

  Dwyer, F. P.; Goodwin, H. A.; Gyarfas, E. C., Australian Journal of Chemistry, 1963, vol. 16, p. 42 - 50

  摘要：

  DOI：
• 作为产物：
  描述：

  水合三氯化钌 在 HCl 、 (C₅H₄N)2 作用下， 以 乙醇 、 水 为溶剂， 以50%的产率得到bpyH{RuCl4(bpy)}
  参考文献：
  名称：

  One-pot and selective synthesis of a series of [RuCl6−2nLn] (L=bidentate ligand, n=0−3) types of complexes with polypyridyl ligands; another example of the synthetic utility of ‘ruthenium-blue’ solution

  摘要：

  Convenient (one-pot) and selective syntheses of a series of ruthenium complexes with polypyridyl ligands, [RuL3]2+, cis-[RuCl2L2]+ and [RuCl4L]- (L=bpy, phen or Hdpa (di-2,2-dipyridylamine)), including [RuCl6]3-, have been reported as further examples of the synthetic utility of 'ruthenium-blue' solution. The methods developed here are also useful for synthesizing selectively such pair complexes as [Ru(III)Cl3(terpy)]-[Ru(II)(terpy)2]2+ and [Ru-(III)Cl4py2]--[Ru(II)Cl2py4].

  DOI：

  10.1016/s0020-1693(00)85316-5

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ru: SVol., 177, page 478 - 480
  作者：

  DOI：——

  日期：——
• Formation of optically active [Ru(bipy)₂Cl₂](bipy = 2,2′-bipyridyl) by photodissociation of [Ru(bipy)₃]Cl₂in dichloromethane
  作者：Akihiko Yamagishi、Kyaw Naing、Yasutomo Goto、Masahiro Taniguchi、Masayuki Takahashi

  DOI：10.1039/dt9940002085

  日期：——

  An optically active bis-chelated complex, [Ru(bipy)2Cl2] (bipy = 2,2'-bipyridyl), has been obtained when enantiomeric [Ru(bipy)3]Cl2 was illuminated by visible light in dichloromethane. From the dependence of the optical purity of the product on light intensity, it is proposed that the reaction from DELTA-[Ru(bipy)3]Cl2 to DELTA-[Ru(bipy)2Cl2] (Chirality retention) proceeds by way of the dissociation of a monodentate ligand, bipy*, from a photoactivated intermediate, DELTA-[Ru(bipy)2(bipy*)Cl]Cl in the dark, while the reaction to LAMBDA-[Ru(bipy)2Cl2] (chirality inversion) involves the further photoactivated configurational change of DELTA-[Ru(bipy)2(bipy*)Cl]Cl to LAMBDA-[Ru(bipy)2(bipy*)Cl]Cl. Racemization is avoided under the conditions of weak light and high temperature. The synthetic value of optically active [Ru(bipy)2Cl2] as a chiral intermediate has been exemplified by preparing a new chiral amphiphilic ruthenium(II) complex.