2-Butyl-4-(3-butyl-4-hydroxy-5-methylphenyl)sulfanyl-6-methylphenol | 87256-88-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2-Butyl-4-(3-butyl-4-hydroxy-5-methylphenyl)sulfanyl-6-methylphenol
• CAS: 87256-88-0
• 化学式: C₂₂H₃₀O₂S
• 分子量: 358.545
• InChiKey: FMQNGHSTJXBUOL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  25
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  65.8
• 氢给体数：
  2
• 氢受体数：
  3

文献信息

• Preparing clindamycin and analogues thereof
  申请人：THE UPJOHN COMPANY

  公开号：EP0161794A2

  公开（公告）日：1985-11-21

  A process for preparing 7-halo-7-deoxylincomycin or an analogue thereof, which comprises (a) reacting a starting compound selected from lincomycin and analogues thereof, with an amide halide having the formula wherein each Hal is bromine or chlorine, and either Ri and R2 are independently selected from aryl and C1-8 alkyl or NR1R2 is morpholino or a heterocyclic ring containing 4 to 8 ring atoms selected from carbon and nitrogen, to form an adduct; (b) heating the adduct, to form a 7-halo-7-deoxy adduct; and (c) hydrolysing the 7-halo-7-deoxy adduct with an aqueous base.

  一种制备 7-卤代-7-脱氧辛霉素或其类似物的工艺，包括 (a) 将选自林可霉素及其类似物的起始化合物与酰胺卤化物反应，酰胺卤化物的 式为 其中每个 Hal 是溴或氯，Ri 和 R2 独立地选自芳基和 C1-8 烷基，或 NR1R2 是吗啉基或含有 4 至 8 个选自碳和氮的环原子的杂环，以形成加合物； (b) 加热加合物，形成 7-卤代-7-脱氧加合物；和 (c) 用水基水解 7-卤代-7-脱氧加合物。
• ETHYLENIC RANDOM COPOLYMER, PROCESS FOR PREPARING THE SAME, AND RUBBER COMPOSITION
  申请人：Mitsui Chemicals, Inc.

  公开号：EP0842957A1

  公开（公告）日：1998-05-20

  A process for preparing an ethylene/α-olefin/norbornene nonconjugated polyene random copolymer, comprising preparing an ethylene random copolymer simultaneously meeting the following requirements (1) to (5): (1) the molar ratio of ethylene (a) to an α-olefin (b) having 3 to 20 carbon atoms ranges from 40:60 to 95:5; (2) a given amount of non conjugated polyene (c) has a norbornene skeleton; (3) the available network chain density ν is not less than 1.5 x 1020/cm3 after press cross-linking of the copolymer using a dicumyl peroxyde; (4) the ratio of the rate γ1 of shear showing a shearing stress of 0.4 x 106 dyn/cm2 as determined from the melt flow curve at 100°C and the rate γ2 of shear showing a shearing stress of 2.4 x 106 dyn/cm2, that is γ2/γ1 and the available network chain density ν has a relationship represented by the following general formula: 0.04 x 10-19 ≤ Log(γ2/γ1)/ν ≤ 0.20 x 10-19; and (5) the intrinsic viscosity [η] ranges from 0.5 to 10 dl/g as measured in decalin at 135°C. The copolymer has excellent cross-linkability, can be cross-linked with a small amount of a peroxide or the like, and a cross-linked rubber composition prepared using this copolymer has excellent heat aging resistance, mechanical strength, weather resistance, and oxone resistance.

  一种制备乙烯/α-烯烃/降冰片烯非共轭聚烯无规共聚物的工艺，包括制备同时满足以下要求（1）至（5）的乙烯无规共聚物： (1) 乙烯（a）与具有 3 至 20 个碳原子的α-烯烃（b）的摩尔比为 40:60 至 95:5； (2) 一定量的非共轭多烯（c）具有降冰片烯骨架； (3) 共聚物在使用二异丙基过氧化物按压交联后，可用网络链密度 ν 不小于 1.5 x 1020/cm3 (4) 根据 100℃熔体流动曲线确定的剪切应力为 0.4×106 达因/厘米2 的剪切速率 γ1 与剪切应力为 2.4×106 达因/厘米2 的剪切速率 γ2，即 γ2/γ1，与可用网络链密度 ν 之比具有以下通式表示的关系：0.04 x 10-19 ≤ Log(γ2/γ1)/ν ≤ 0.20 x 10-19；以及 (5) 本征粘度[η]范围为 0.5 至 10 dl/g（在 135°C 的癸醛中测量）。该共聚物具有优异的交联性，可与少量过氧化物或类似物交联，使用该共聚物制备的交联橡胶组合物具有优异的耐热老化性、机械强度、耐候性和耐氧化性。
• Rubber composition for a conveyor belt
  申请人：Mitsui Chemicals, Inc.

  公开号：EP0877053A2

  公开（公告）日：1998-11-11

  According to the present invention, there is provided a rubber composition for a conveyor belt comprising (A) 100 parts by weight of an ethylene/a-olefin containing 3 to 20 carbon atoms/non-conjugated polyene copolymer rubber containing a diene unit derived from special non-conjugated dienes, (B) 0.5 to 15 parts by weight of an organic peroxide, (C) 30 to 80 parts by weight of a carbon black and (D) 5 to 25 parts by weight of a softening agent.

  根据本发明，提供了一种用于传送带的橡胶组合物，该组合物包括：(A) 100 份（按重量计）含 3 至 20 个碳原子的乙烯/烯烃/非共轭聚烯共聚物橡胶（含源自特殊非共轭二烯的二烯单元）；(B) 0.5 至 15 份（按重量计）有机过氧化物；(C) 30 至 80 份（按重量计）炭黑；(D) 5 至 25 份（按重量计）软化剂。
• A crosslinkable polyolefin composition
  申请人：UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

  公开号：EP0965999A1

  公开（公告）日：1999-12-22

  A composition comprising: (a) polyolefin; (b) as a scorch inhibitor, 4,4'-thiobis(2-methyl-6-t-butyl phenol); 2,2'-thiobis(6-t-butyl-4-methylphenol); or mixtures thereof; (c) hydroquinone; a substituted hydroquinone ; or mixtures thereof in an amount sufficient to control color formation; and (d) an organic peroxide.

  一种组合物，包括 (a) 聚烯烃； (b) 作为焦烧抑制剂的 4,4'-硫代双(2-甲基-6-叔丁基苯酚)； 2,2'-硫代双(6-叔丁基-4-甲基苯酚)；或它们的混合物； (c) 对苯二酚；取代的对苯二酚；或其混合物，其用量足以控制颜色的形成； 以及 (d) 有机过氧化物。
• Rubber compositions and their uses
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1245623A1

  公开（公告）日：2002-10-02

  This invention relates to a composition comprising (A) an ethylene - α -olefin having 3 to 20 carbon atoms-non-conjugated polyene copolymer, (B) a specific fine-powdered silicic acid and/or a silicate having a specific surface area of 5 to 500 m2/g (BET adsorption amount: ISO 5794/1, Annex D), (C) at least one kind of α,β-unsaturated carboxylic acid metal salts, (D) an organic peroxide, further optionally (E) one antioxidant selected from sulfur-containing antioxidants, phenolic antioxidants and amine antioxidants, and/or (F) sulfur, and this invention relates to a rubber product obtainable by crosslinking the above composition.

  本发明涉及一种组合物，该组合物包括：(A) 具有 3 至 20 个碳原子的乙烯-α-烯烃-非共轭聚烯共聚物；(B) 比表面积为 5 至 500 m2/g 的特定细粉状硅酸和/或硅酸盐（BET 吸附量：ISO 5794/1，附件 D），(C) 至少一种 α，β-不饱和羧酸金属盐，(D) 一种有机过氧化物，还可选择 (E) 一种选自含硫抗氧化剂、酚类抗氧化剂和胺类抗氧化剂的抗氧化剂，和/或 (F) 硫，本发明涉及一种通过交联上述组合物获得的橡胶产品。