| 1194952-82-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1194952-82-3
• 化学式: C₅₈H₆₂LuN₃P₂Si₂
• 分子量: 1094.24
• InChiKey: XNJQHSTUAYKTNZ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  以 氘代甲苯 为溶剂， 生成 [(1,8-(C6H4(Ph)P=NPh)2-3,6-dimethylcarbazolide-κ3N)Lu(THF)]
  参考文献：
  名称：

  Synthesis and Reactivity of Dialkyl Lutetium Complexes Supported by a Novel Bis(phosphinimine)carbazole Pincer Ligand

  摘要：

  The synthesis of a novel bis(phosphinimine) ancillary ligand based on a carbazole framework is described (HLPh, 4a; HLPipp, 4b; Ph = phenyl, Pipp = para-isopropylphenyl). Protonolysis with Lu-(CH2SiMe3)(3)(THF)(2) afforded the corresponding lutetium dialkyl complexes (LuLPh(CH2SiMC3)(2), 5a; LuLPipp(CH2SiMe3)(2), 5b), which were thermally sensitive and rapidly underwent intramolecular metalative alkane elimination to generate LuLPh*(CH2SiMC3)(THF), 6a, and LuLPipp*(CH2SiMe3)-(THF), 6b, as highly reactive intermediates. Complexes 6a and 6b further decomposed, cleanly generating doubly metalated complexes LuLPh**(THF), 7a, and LuLPipp**(THF), 7b, respectively, as the thermodynamic products. Kinetic analysis of the decomposition of 5a revealed a first-order mechanism with activation parameters Delta H = 19.2(l) kcal. mol(-1) and Delta S* = -8.2(2) cal.K-1.mol(-1). Compounds 4a, 4b, 6b, and 7b were characterized by single-crystal X-ray diffraction studies.

  DOI：

  10.1021/om900731x
• 作为产物：
  描述：

  Lu(trimethylsilylmethyl)3(tetrahydrofuran)2 、 [8-[diphenyl(phenylimino)-lambda5-phosphanyl]-3,6-dimethyl-9H-carbazol-1-yl]-diphenyl-phenylimino-lambda5-phosphane 以 氘代甲苯 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Reactivity of Dialkyl Lutetium Complexes Supported by a Novel Bis(phosphinimine)carbazole Pincer Ligand

  摘要：

  The synthesis of a novel bis(phosphinimine) ancillary ligand based on a carbazole framework is described (HLPh, 4a; HLPipp, 4b; Ph = phenyl, Pipp = para-isopropylphenyl). Protonolysis with Lu-(CH2SiMe3)(3)(THF)(2) afforded the corresponding lutetium dialkyl complexes (LuLPh(CH2SiMC3)(2), 5a; LuLPipp(CH2SiMe3)(2), 5b), which were thermally sensitive and rapidly underwent intramolecular metalative alkane elimination to generate LuLPh*(CH2SiMC3)(THF), 6a, and LuLPipp*(CH2SiMe3)-(THF), 6b, as highly reactive intermediates. Complexes 6a and 6b further decomposed, cleanly generating doubly metalated complexes LuLPh**(THF), 7a, and LuLPipp**(THF), 7b, respectively, as the thermodynamic products. Kinetic analysis of the decomposition of 5a revealed a first-order mechanism with activation parameters Delta H = 19.2(l) kcal. mol(-1) and Delta S* = -8.2(2) cal.K-1.mol(-1). Compounds 4a, 4b, 6b, and 7b were characterized by single-crystal X-ray diffraction studies.

  DOI：

  10.1021/om900731x