H2pcH(1+) | 1068661-87-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: H2pcH(1+)
• 英文别名: 2,11,20,29,37,38,39-Heptaza-40-azonianonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene
• CAS: 1068661-87-9
• 化学式: C₃₂H₁₈N₈*H
• 分子量: 515.556
• InChiKey: IEQIEDJGQAUEQZ-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  40
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  103
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  Rh(pc-H)(HSO4) 在 oxonium 作用下， 生成 、 H2pcH(1+)
  参考文献：
  名称：

  Berezin, B. D., Doklady Akademii nauk SSSR, 1963, vol. 148/153, p. 478 - 481

  摘要：

  DOI：

文献信息

• MIXED CRYSTAL AND COLORED PIGMENT DISPERSION COMPOSITION
  申请人：Tanaka Shigeaki

  公开号：US20110023752A1

  公开（公告）日：2011-02-03

  The present invention provides a mixed crystal having absorption properties that are excellent for color reproducibility as a blue pigment, and including a compound represented by the following Formula (I) and a compound represented by the following Formula (II), and a colored pigment dispersion composition including the mixed crystal and a medium. In Formula (I), X represents —SO—Z, —SO 2 —Z, —SO 2 NR 1 R 2 , —SO 3 R 1 , —CONR 1 R 2 or —CO 2 R 1 ; Z, R 1 and R 2 each independently represent an alkyl group, an aryl group, a heterocyclic group or the like; Y represents a monovalent substituent; M 1 represents a hydrogen atom, a metal element or the like; and a and b are integers from 0 to 16 and satisfy the relationship of 0≦a+b≦16. In Formula (II), G 1 to G 4 and Q 1 to Q 4 each independently represent a carbon atom or a nitrogen atom, and A 1 to A 4 each independently represent a group of atoms necessary for forming an aromatic ring or heterocycle with the respective G 1 to G 4 and Q 1 to Q 4 . Here, at least one ring among the four rings to be formed is a heterocycle. Each aromatic ring or heterocycle may have a substituent; M 2 represents a hydrogen atom, a metal element or the like.

  本发明提供了一种混合晶体，其吸收性能在作为蓝色颜料的颜色再现性方面表现出色，并包括由以下式（I）表示的化合物和由以下式（II）表示的化合物以及包括所述混合晶体和介质的着色颜料分散组合物。在式（I）中，X表示—SO—Z，—SO2—Z，—SO2NR1R2，—SO3R1，—CONR1R2或—CO2R1；Z、R1和R2各自独立地表示烷基、芳基、杂环基或类似物；Y表示单价取代基；M1表示氢原子、金属元素或类似物；a和b是0到16的整数，并满足0≦a+b≦16的关系。在式（II）中，G1到G4和Q1到Q4各自独立地表示碳原子或氮原子，A1到A4各自独立地表示与各自的G1到G4和Q1到Q4形成芳香环或杂环所必需的原子团。在这里，要形成的四个环中至少有一个是杂环。每个芳香环或杂环可以具有取代基；M2表示氢原子、金属元素或类似物。
• Method for producing phtahlocyanine photosensitive material
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP0661353A2

  公开（公告）日：1995-07-05

  A phthalocyanine mixed crystal composed of at least two or more phthalocyanines selected from hydrogen phthalocyanine, copper phthalocyanine, titanyl phthalocyanine and vanadyl phthalocyanine is made to exist in water and/or an alcohol along with an organic solvent having a relative permittivity of 20 or less. The solution containing these components is optionally stirred and then allowed to stand as it is for a pre-determined period of time, whereupon the crystal structure of the phthalocyanine mixed crystal therein is converted. The phthalocyanine mixed crystal, of which the crystal structure has been converted, is washed with water or an alcohol, then filtered out and dried. The thus-obtained phthalocyanine photosensitive material is used to produce a photoreceptor, which can output digital signals at any time by digital inputting or analogical inputting. Therefore, the photoreceptor can be used in digital recording photography and also as a conventional analogical input photoreceptor to give high-quality images having sharp edges.

  酞菁混合晶体由至少两种或两种以上的酞菁组成，这些酞菁选自氢酞菁、铜酞菁、钛 酞菁和钒酞菁，它们与相对介电常数为 20 或更小的有机溶剂一起存在于水和/或酒精中。将含有这些成分的溶液搅拌均匀，然后按原样放置一段预定的时间，其中的酞菁混合晶体的晶体结构就会发生转变。用水或酒精清洗晶体结构已经转换的酞菁混合晶体，然后过滤并干燥。由此获得的酞菁光敏材料可用于生产光敏器，该光敏器可通过数字输入或模拟输入随时输出数字信号。因此，这种感光元件既可用于数字记录摄影，也可用作传统的模拟输入感光元件，以提供边缘清晰的高质量图像。
• Thin film transistor based on substituted phthalocyanines
  申请人：LUCENT TECHNOLOGIES INC.

  公开号：EP0921579A2

  公开（公告）日：1999-06-09

  Thin film, n-channel transistors in which the active layer is an ordered film of a substituted phthalocyanine coordination compound with a field-effect mobility greater than 10-3 cm2/Vs and a conductivity in the range of about 10-9 S/cm to about 10-7 S/cm at 20°C are disclosed. Examples of suitable substituted phthalocyanines include copper phthalocyanine, zinc phthalocyanine, hydrogen phthalocyanine, and tin phthalocyanine in which the phthalocyanine has at least one fluorine or chlorine substituent on at least one of its six-membered rings. Thin film devices made of these materials have an on/off ratio of at least about 103. It is advantageous if the device is fabricated using a process in which the substrate is heated to a temperature in the range of about 30°C to about 215°C when the film is formed thereon.

  本发明公开了薄膜 n 沟道晶体管，其中的有源层是取代酞菁配位化合物的有序薄膜，在 20°C 时，其场效应迁移率大于 10-3 cm2/Vs，电导率在约 10-9 S/cm 至约 10-7 S/cm 范围内。合适的取代酞菁的例子包括铜酞菁、锌酞菁、氢酞菁和锡酞菁，其中酞菁的至少一个六元环上有至少一个氟或氯取代基。由这些材料制成的薄膜器件的开/关比率至少约为 103。如果使用这样的工艺来制造器件则更为有利，即在基底上形成薄膜时，将基底加热到约 30°C 至约 215°C 的温度范围内。
• PHOTOELECTRON MEASURING DEVICE
  申请人：RIKEN KEIKI CO., LTD.

  公开号：EP1724571A1

  公开（公告）日：2006-11-22

  To provide a photoelectron measuring device that enables handling of samples in the atmosphere. A photoelectron measuring device that emits ultraviolet light from an ultraviolet light generating source 1 onto a sample S while changing the wavelength and detects the wavelength at which photoelectrons start to be discharged from the sample S, with the section up to an emission outlet 2 being housed in a non-oxygen environment and a sample stand 4 being disposed so that the distance from the emission outlet 2 to the sample S is 7 mm or less.

  提供一种可在大气中处理样品的光电子测量装置。 一种光电子测量装置，它能从紫外光发生源 1 向样品 S 发射紫外光，同时改变波长，并检测从样品 S 开始放出光电子的波长，其中到发射出口 2 的部分被置于非氧环境中，而样品架 4 的布置则使发射出口 2 到样品 S 的距离小于或等于 7 毫米。
• Manufacturing process for dark-color polymer composite films
  申请人：Nanotek Instruments, Inc.

  公开号：US11186704B2

  公开（公告）日：2021-11-30

  Provided is a process for producing a polymer composite film, comprising the steps of: (a) mixing a phthalocyanine compound with a polymer or its precursor and a liquid to form a slurry and forming the slurry into a wet film on a solid substrate, wherein the polymer is preferably selected from the group consisting of polyimide, polyamide, polyoxadiazole, polybenzoxazole, polybenzobisoxazole, polythiazole, polybenzothiazole, polybenzobisthiazole, poly(p-phenylene vinylene), polybenzimidazole, polybenzobisimidazole, and combinations thereof; and (b) removing the liquid from the wet film and, in some embodiments, converting the precursor to the polymer to form the polymer composite film comprising from 0.1% to 50% by weight of the phthalocyanine compound dispersed in the polymer.

  本发明提供了一种生产聚合物复合薄膜的工艺，包括以下步骤(a) 将酞菁化合物与聚合物或其前体和液体混合形成浆料，并将浆料在固体基底上形成湿膜，其中聚合物优选选自由聚酰亚胺组成的组、聚酰胺、聚噁二唑、聚苯并噁唑、聚苯并异噁唑、聚噻唑、聚苯并噻唑、聚苯并异噻唑、聚对苯乙烯、聚苯并咪唑、聚苯并异咪唑及其组合；(b) 从湿膜中除去液体，并在某些实施例中，将前体转化为聚合物，以形成聚合物复合膜，该膜包含 0.1%至50%（按重量计）的酞菁化合物分散在聚合物中。