CrMe[N(SiMe2CH2PPh2)2](SPh) | 197171-53-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: CrMe[N(SiMe2CH2PPh2)2](SPh)
• 英文别名: Benzenethiolate;bis[diphenylphosphanylmethyl(dimethyl)silyl]azanide;carbanide;chromium(3+)
• CAS: 197171-53-2
• 化学式: C₃₇H₄₄CrNP₂SSi₂
• 分子量: 704.944
• InChiKey: OHQITHUSAMKPAQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  9.15
• 重原子数：
  44
• 可旋转键数：
  11
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  Bis[diphenylphosphanylmethyl(dimethyl)silyl]azanide;carbanide;chromium(2+) 、 二苯二硫醚 以 甲苯 为溶剂， 以66%的产率得到CrMe[N(SiMe2CH2PPh2)2](SPh)
  参考文献：
  名称：

  Synthesis and Structure of a Five-Coordinate Organochromium(III) Thiolate Complex from a Chromium(II) Alkyl Precursor

  摘要：

  The reaction of the Cr(II) methyl complex, CrMe[N(SiMe2CH2PPh2)(2)], with diphenyl disulfide (PhSSPh) leads to the formation of the five-coordinate, paramagnetic complex CrMe(SPh)[N(SiMe2CH2PPh2)(2)] by an overall one-electron oxidation. The complex is unusual in that the phenyl thiolate moiety is terminal and does not engage in bridging to generate a dinuclear system having octahedral Cr(III) centers. The complex was characterized both in solution and in the solid state.

  DOI：

  10.1021/om970574l