tetrakis(furo[3,2-c]pyridine)bis(isothiocyanato)nickel(II) tetahydrofuran monosolvate | 748145-58-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并吡啶类
• 英文名称: tetrakis(furo[3,2-c]pyridine)bis(isothiocyanato)nickel(II) tetahydrofuran monosolvate
• 英文别名: trans-[Ni(II)(furo[3,2-c]pyridine)4(isothiocyanate)2]*THF
• CAS: 748145-58-6
• 化学式: C₄H₈O*C₃₀H₂₀N₆NiO₄S₂
• 分子量: 723.456
• InChiKey: JMDBTTSFKMWWIZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 nickel(II) chloride hexahydrate 、 potassium thioacyanate 、 呋喃[3,2-c]吡啶 以 乙醇 为溶剂， 生成 tetrakis(furo[3,2-c]pyridine)bis(isothiocyanato)nickel(II) tetahydrofuran monosolvate
  参考文献：
  名称：

  Structural characterization, spectral and magnetic properties of isothiocyanate nickel(II) complexes with furopyridine derivatives

  摘要：

  Nickel(II) complexes of the formula [Ni(L-n)(4)(NCS)(2)], (where L-n are derivatives of furo[3,2-c]pyridine, L-1 = furo[3,2-c]pyridine, L-2 = 2-methylfuro[3,2-c]pyridine, L-3 = 2,3-dimethylfuro[3,2-c]pyridine and L-4 = benzo[4,5]furo[3,2-c]pyridine) have been prepared and characterized by spectroscopic methods and magnetic measurements. For comparative reasons, L-5 = isoquinoline has also been involved. The crystal and molecular structures of [Ni(L-2)(4)(NCS)(2)], [Ni(L-4)(4)(NCS)(2)] and [Ni(L-5)(4)(NCS)(2)] have been determined by X-ray diffractions methods. The structures of all the complexes are formed by isolated molecules. The Ni(II) ions are six-coordinate, the equatorial planes are formed by four N-donor furopyridines whereas the isothiocyanate groups coordinate in the axial positions. The magnetism of the complexes exhibits a zero-field splitting, the magnitude of which correlates with the distortion degree of the coordination polyhedra. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.03.103