[Co2(benzene-1,2,4,5-tetracarboxylate)(H2O)10]*H2O | 1174539-35-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Co2(benzene-1,2,4,5-tetracarboxylate)(H2O)10]*H2O
• CAS: 1174539-35-5
• 化学式: C₁₀H₂₂Co₂O₁₈*H₂O
• 分子量: 566.276
• InChiKey: MMGXZVNWHQMVBV-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  (K2[Co3(benzene-1,2,4,5-tetracarboxylate)2(H2O)4]*6H2O)n 在 lithium chloride 作用下， 以 水 为溶剂， 以35%的产率得到[Co2(benzene-1,2,4,5-tetracarboxylate)(H2O)10]*H2O
  参考文献：
  名称：

  溶解/重组对多孔钴（II）-和镍（II）-羧酸盐配位聚合物的破坏/构造

  摘要：

  碱金属阳离子诱导的多孔配位聚合物（CP）{A 2 [M 3（btec）2（H 2 O）4 ]} n（1，A = K，M = Co; 2， A = K，M = Ni；3，A = Cs，M = Co；以及4，A = Cs，M = Ni； btec =苯-1,2,4,5-四羧酸酯），是通过独特的溶解/在水中存在碱金属氯化物（LiCl，NaCl）的情况下进行重组过程。在LiCl水溶液中处理1或2导致形成新的金属羧酸盐物种[Co 2（btec）（H 2O）10 ]·H 2 O（5 ·H 2 O）和{Li 2 [Ni 3（btec）2（H 2 O）10 ]·3.5H 2 O} n（6 ·3.5H 2 O）分别。当在相似的反应条件下使用NaCl代替LiCl时，观察到相似的溶解/重组过程。钴物种1和3被转化为金属羧酸盐产物[Na 2 Co（btec）（H 2 O）8 ] n（7），而将羧酸镍镍骨架2和4转化为{[Na

  DOI：

  10.1021/ic900037g

文献信息

• Study of the aqueous reactions of metallic ions with benzenetetracarboxylate ions
  作者：Fernande D Rochon、Gassan Massarweh

  DOI：10.1016/s0020-1693(01)00307-3

  日期：2001.3

  The reactions of barium 1,2,4,5-benzenetetracarboxylate with CoSO4 produced the dinuclear species Co(H2O)(5)(mu -C6H2(COO)(4))Co(H2O)(5) which was characterized by crystallographic methods. The results have shown that the compound belongs to the monoclinic C2/c space group and it crystallized with six molecules of water in the lattice. The crystal is stabilized by a very elaborate H-bonded 3D network. The molecule contains an inversion center. The average Co-OH2 distance is 2.0710(8) Angstrom and the sixth Co-O bond is 2.0356(7) Angstrom. The reaction of MnCl2 with benzenetetracarboxylate ions produced a similar dinuclear species, Mn(H2O)(5)(mu -C6H2(COO)(4))Mn(H2O)(5).H2O (2). The crystallographic results have shown that there are two independent molecules, which each contains an inversion center. This compound crystallized with only one molecule of water, and again the H-bonding system is very elaborate. The aqueous reaction of K2Mn(C6H2(COO)(4)). 3H(2)O with CoSO4 produced a compound containing two dinuclear species Mn(H2O)(5)(mu -C6H2(COO)(4))Mn(H2O)(5)} Co(H2O)(5)(mu -C6H2(COO)(4))Co(H2O)(5)}. 2H(2)O, which was characterized by X-ray diffraction methods. The results have shown that the latter compound is isomorphous with the Mn(II) compound. One of the Mn(II) dimer in 2 has been replaced by a Co(II) dimer. (C) 2001 Elsevier Science B.V. All rights reserved.