decaaqua(μ-1,2,4,5-benzenetetracarboxylato-O(1):O(4))dimanganese(II) monohydrate | 271789-52-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: decaaqua(μ-1,2,4,5-benzenetetracarboxylato-O(1):O(4))dimanganese(II) monohydrate
• 英文别名: Mn(H2O)5(μ-1,2,4,5-benzenetetracarboxylato)Mn(H2O)5 monohydrate
• CAS: 271789-52-7
• 化学式: C₁₀H₂₂Mn₂O₁₈*H₂O
• 分子量: 558.165
• InChiKey: IJRAHKCYJFFQCA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  barium 1,2,4,5-benzenetetracarboxylate 、 manganese(ll) chloride 在 4,4'-trimethylenedipyridine 、 KOH 作用下， 以 水 为溶剂， 生成 decaaqua(μ-1,2,4,5-benzenetetracarboxylato-O(1):O(4))dimanganese(II) monohydrate
  参考文献：
  名称：

  Study of the aqueous reactions of metallic ions with benzenetetracarboxylate ions

  摘要：

  The reactions of barium 1,2,4,5-benzenetetracarboxylate with CoSO4 produced the dinuclear species Co(H2O)(5)(mu -C6H2(COO)(4))Co(H2O)(5) which was characterized by crystallographic methods. The results have shown that the compound belongs to the monoclinic C2/c space group and it crystallized with six molecules of water in the lattice. The crystal is stabilized by a very elaborate H-bonded 3D network. The molecule contains an inversion center. The average Co-OH2 distance is 2.0710(8) Angstrom and the sixth Co-O bond is 2.0356(7) Angstrom. The reaction of MnCl2 with benzenetetracarboxylate ions produced a similar dinuclear species, Mn(H2O)(5)(mu -C6H2(COO)(4))Mn(H2O)(5).H2O (2). The crystallographic results have shown that there are two independent molecules, which each contains an inversion center. This compound crystallized with only one molecule of water, and again the H-bonding system is very elaborate. The aqueous reaction of K2Mn(C6H2(COO)(4)). 3H(2)O with CoSO4 produced a compound containing two dinuclear species {Mn(H2O)(5)(mu -C6H2(COO)(4))Mn(H2O)(5)} {Co(H2O)(5)(mu -C6H2(COO)(4))Co(H2O)(5)}. 2H(2)O, which was characterized by X-ray diffraction methods. The results have shown that the latter compound is isomorphous with the Mn(II) compound. One of the Mn(II) dimer in 2 has been replaced by a Co(II) dimer. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00307-3

文献信息

• A binuclear manganese(II) complex, decaaqua(μ-1,2,4,5-benzenetetracarboxylato-O1:O4)dimanganese(II) hydrate
  作者：Deping Cheng、Yueqing Zheng、Jianli Lin、Duanjun Xu、Yuanzhi Xu

  DOI：10.1107/s0108768100000343

  日期：2000.5.15