Hetero-bimetallic dinitrogen activation: X-ray structure of the (Me3P)3CoN2AlMe2 dimer
作者:Hans F. Klein、Klaus Ellrich、Klaus Ackermann
DOI:10.1039/c39830000888
日期:——
Dinitrogen forms a push–pull stabilized double bond [125.2(6) pm] when one end is bound to an electron-rich cobalt complex and the other end is part of an N2Al2 ring in the (Me3P)3 CoN2AlMe2 dimer, the structure of which has been found by X-ray crystallography.
当一个末端与富电子的钴配合物结合且另一末端为(Me 3 P)3 CoN中的N 2 Al 2环的一部分时,二氮形成一个推挽稳定的双键[125.2(6)pm] 。2 AlMe 2二聚体,其结构已通过X射线晶体学发现。