One-pot and selective synthesis of a series of [RuCl6−2nLn] (L=bidentate ligand, n=0−3) types of complexes with polypyridyl ligands; another example of the synthetic utility of ‘ruthenium-blue’ solution
                                
                                    
                                        作者:Tadashi Togano、Noriharu Nagao、Mitsuko Tsuchida、Hiromi Kumakura、Kumiko Hisamatsu、F.Scott Howell、Masao Mukaida                                    
                                    
                                        DOI:10.1016/s0020-1693(00)85316-5
                                    
                                    
                                        日期:1992.5
                                    
                                    Convenient (one-pot) and selective syntheses of a series of ruthenium complexes with polypyridyl ligands, [RuL3]2+, cis-[RuCl2L2]+ and [RuCl4L]- (L=bpy, phen or Hdpa (di-2,2-dipyridylamine)), including [RuCl6]3-, have been reported as further examples of the synthetic utility of 'ruthenium-blue' solution. The methods developed here are also useful for synthesizing selectively such pair complexes as [Ru(III)Cl3(terpy)]-[Ru(II)(terpy)2]2+ and [Ru-(III)Cl4py2]--[Ru(II)Cl2py4].