2,4-trichloromethyl-(4'-methylbiphenyl)-6-triazine | 539854-53-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-trichloromethyl-(4'-methylbiphenyl)-6-triazine
• 英文别名: 2,4-bis-trichloromethyl-6-(4'-methyl-biphenyl-1-4yl)-[1,3,5]triazine；2-(4'-Methyl[1,1'-biphenyl]-4-yl)-4,6-bis(trichloromethyl)-1,3,5-triazine；2-[4-(4-methylphenyl)phenyl]-4,6-bis(trichloromethyl)-1,3,5-triazine
• CAS: 539854-53-0
• 化学式: C₁₈H₁₁Cl₆N₃
• 分子量: 482.023
• InChiKey: GAIXIQROKLDDGK-UHFFFAOYSA-N

物化性质

• 沸点：
  533.9±60.0 °C(Predicted)
• 密度：
  1.512±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,4-trichloromethyl-(4'-methylbiphenyl)-6-triazine 在 N-溴代丁二酰亚胺(NBS) 、 偶氮二异丁腈 作用下， 以 四氯化碳 为溶剂， 反应 2.0h， 以84%的产率得到2,4-bis-trichloromethyl-6-(4'-dibromomethyl-biphenyl-4-yl)-[1,3,5]triazine
  参考文献：
  名称：

  Triazine based photoactive compound containing oxime ester

  摘要：

  本发明涉及一种三嗪基光活性化合物，其中包含一个肟酯基团。根据本发明的化合物是一种光活性化合物，它在一个分子中同时包含肟酯基团和三嗪基团，由于有效吸收紫外辐射，特别是i线（365纳米）辐射，具有优异的自由基产生效率，并可作为各种含有不饱和基团的化合物，特别是丙烯酰基化合物的光聚合的有效引发剂。

  公开号：

  US20070106075A1

文献信息

• FOAMED PRODUCT IN A SHEET FORM AND METHOD FOR PRODUCTION THEREOF
  申请人：OJI PAPER CO., LTD.

  公开号：EP1647570A1

  公开（公告）日：2006-04-19

  The present invention discloses a foam sheet and its production process comprising the formation of a plurality of independent cells and/or a plurality of continuous cells. The foam sheet is produced from a foamable composition that contains an acid generator that generates an acid or a base generator that generates a base due to the action of an active energy beam and a compound that has a decomposing foamable functional group that decomposes and eliminates one or more types of low boiling point volatile substances by reacting with the acid or base.

  本发明公开了一种泡沫板及其生产工艺，包括形成多个独立单元和/或多个连续单元。泡沫板由一种可发泡组合物生产而成，该组合物含有一种酸发生器（在活性能量束的作用下产生一种酸）或一种碱发生器（在活性能量束的作用下产生一种碱），以及一种化合物，该化合物具有一种可分解泡沫的官能团，通过与酸或碱反应，分解并消除一种或多种低沸点挥发性物质。
• PROCESS FOR PRODUCING FOAM
  申请人：OJI PAPER CO., LTD.

  公开号：EP1795553A1

  公开（公告）日：2007-06-13

  A foam production method including an irradiating step in which an active energy beam is irradiated onto a foamable composition containing an acid generating agent, which generates an acid, or a base generating agent, which generates a base, due to an action of an active energy beam, and containing a compound which has a decomposable/foamable functional group, which decomposes and eliminates one or more kinds of volatile substances with a low boiling point by reacting with the acid or base; and a subsequent foaming step in which the foamable composition is foamed under controlled pressure in a temperature region where the volatile substances with a low boiling point are decomposed and being eliminated.

  一种泡沫生产方法，包括一个辐照步骤，在该步骤中，一束活性能量光束被照射到一种可发泡组合物上，该组合物含有一种酸生成剂，在活性能量光束的作用下生成一种酸，或一种碱生成剂，在活性能量光束的作用下生成一种碱，该组合物还含有一种具有可分解/可发泡官能团的化合物，该化合物通过与酸或碱反应，分解并消除一种或多种具有低沸点的挥发性物质；以及随后的发泡步骤，在该步骤中，可发泡组合物在受控压力下，在低沸点挥发性物质被分解和消除的温度区域内发泡。
• HIGHLY SOLUBLE TRIS-(2,3-EPOXYPROPYL)-ISOCYANURATE AND METHOD FOR PRODUCING SAME
  申请人：Nissan Chemical Corporation

  公开号：EP3543234A1

  公开（公告）日：2019-09-25

  There is provided an epoxy composition which has difficulty in precipitating a crystal during storage, is homogeneous and can be stored for a long period; and a cured product of the composition having excellent transparency, heat resistance, and light resistance can be obtained on curing. The curable composition comprises an a-type tris-(2,3-epoxypropyl)-isocyanurate crystal comprising β-type tris-(2,3-epoxypropyl)-isocyanurate in the crystal in a ratio of 2% by mass to 15% by mass; and a carboxylic acid anhydride in a ratio of 0.5 molar equivalent to 1.5 molar equivalent relative to 1 molar equivalent of the crystal, or a cationic curable compound in a ratio of 0.2 molar equivalent to 5 molar equivalent relative to 1 molar equivalent of the crystal, wherein a solid content concentration is 1% by mass to 99% by mass, wherein the solid content ratio is a ratio of the ingredient after removing a solvent from a solution containing the above compounds.

  本发明提供了一种环氧树脂组合物，该组合物在贮存过程中很难析出晶体，且均匀，可长期贮存；固化后可获得透明度、耐热性和耐光性极佳的固化物。该可固化组合物包括 a 型三-(2,3-环氧丙基)-异氰尿酸盐晶体，晶体中的 β 型三-(2,3-环氧丙基)-异氰尿酸盐的质量比为 2% 至 15%；以及羧酸酐，相对于 1 摩尔当量的晶体，其质量比为 0.5 摩尔当量至 1.5 摩尔当量，或阳离子可固化化合物，其质量比为 0.2摩尔当量至5摩尔当量的阳离子可固化化合物，其中固体含量浓度为1%(质量)至99%(质量)，其中固体含量比率是从含有上述化合物的溶液中去除溶剂后的成分比率。
• Foamed product in a sheet form and method for production thereof
  申请人：Takada Tomoyuki

  公开号：US20060210785A1

  公开（公告）日：2006-09-21

  The present invention discloses a foam sheet and its production process comprising the formation of a plurality of independent cells and/or a plurality of continuous cells. The foam sheet is produced from a foamable composition that contains an acid generator that generates an acid or a base generator that generates a base due to the action of an active energy beam and a compound that has a decomposing foarmable functional group that decomposes and eliminates one or more types of low boiling point volatile substances by reacting with the acid or base.

  本发明公开了一种泡沫板及其生产工艺，包括形成多个独立单元和/或多个连续单元。泡沫板由一种可发泡组合物生产而成，该组合物含有一种酸发生器（在活性能量束的作用下产生一种酸）或一种碱发生器（在活性能量束的作用下产生一种碱），以及一种化合物，该化合物具有一种可分解泡沫的官能团，通过与酸或碱反应，分解并消除一种或多种低沸点挥发性物质。
• WO2007/52987
  申请人：——

  公开号：——

  公开（公告）日：——