Cu(Gly-Phe) | 134572-30-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cu(Gly-Phe)
• CAS: 134572-30-8
• 化学式: C₁₁H₁₂CuN₂O₃
• 分子量: 283.774
• InChiKey: GSYLJTNKIFGBLB-SBSPUUFOSA-L

反应信息

• 作为反应物：
  描述：

  1,10-菲罗啉 、 Cu(Gly-Phe) 生成 Cu(Gly-Phe)(phen)*3H2O
  参考文献：
  名称：

  Synthesis, characterization and superoxide dismutase activity of some ternary copper(II) dipeptide-2,2′-bipyridine, 1,10-phenanthroline and 2,9-dimethyl-1,10-phenanthroline complexes

  摘要：

  Several complexes of 2,2'-bipyridine, 1,10-phenanthroline and 2,9-dimethyl-1,10-phenanthroline with copper(II) dipeptides have been synthesized. These complexes are neutral and show a broad absorption band in the range 630-640 nm due to d-d transition. The solution and glassy state ESR spectra of the complexes have been measured at 301 and 77 K, respectively. The magnetic and bonding parameters of these complexes have been calculated from the above data. The ESR spectral data suggest that these complexes have distorted square pyramidal geometry about Cu(II). The superoxide dismutase activity of several of the above complexes has been measured. They show higher activity than the corresponding CU(II) dipeptide complexes because of a strong axial bond of one of the nitrogen atoms of the alpha-diimine.

  DOI：

  10.1016/s0020-1693(00)85383-9