名称:
                                Synthesis and Spectrophotometric studies of the La3+, Ce3+, Nd3+, Th4+and UO22+Complexes of Some Thiohydantoin Derivatives of Azo Dyes
                             
                            
                                摘要:
                                Complexes of La3+, Ce3+, Nd3+, Th4+ and UO22+ with some derivatives of o-hydroxyphenylazo-1-methyl-3-phenyl-2-thiohydantoin have been investigated in solution by using spectrophotometric and conductometric titration methods. The composition of the complexes was determined to be 1:1 and 1:2 (M:L). The optimum conditions favouring the formation of the coloured complexes were studied extensively and their stability constants determined. Adherence to Beer's law was observed for the ppm concentration range. Spectrophotometric titration methods for La3+, Ce3+, Nd3+, Th4+ and UO22+ with EDTA in the presence of the ligand as an indicator are reported as are interferences by several metal ions. The solid complexes have been characterized by elemental analyses, thermal methods (DTA and TGA), IR and solution H-1 NMR spectra.