| 1035222-41-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• CAS: 1035222-41-3
• 化学式: C₄₁H₂₈O₄
• 分子量: 584.671
• InChiKey: PKEDYMIAEJKTJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  45
• 可旋转键数：
  0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  80.9
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  5',5'',6',6''-tetramethoxy-2'H,2''H-trispiro[fluorene-9,1'-indene-3',1''-indene-3'',9'''-fluorene] 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Novel Spirobisindanes for Use as Precursors to Polymers of Intrinsic Microporosity

  摘要：

  The synthesis of novel spirobisindane-based monomers for the preparation of polymers of intrinsic microporosity (PIMs) with bulky, rigid substituents is described. Polymers derived from monomers containing spiro-linked fluorene substituents display enhanced solubility and microporosity due to additional frustration of packing in the solid state.

  DOI：

  10.1021/ol800573m

文献信息

• [EN] LADDER POLYMERS WITH INTRINSIC MICROPOROSITY AND PROCESS FOR PRODUCTION THEREOF<br/>[FR] POLYMÈRES ÉCHELLE DOTÉS D'UNE MICROPOROSITÉ INTRINSÈQUE ET LEUR PROCÉDÉ DE PRODUCTION
  申请人：CA NAT RESEARCH COUNCIL

  公开号：WO2010048694A1

  公开（公告）日：2010-05-06

  A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both -CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.

  一种化学式（I）的聚合物：其中：n为10至5,000之间的整数；m为10至5,000之间的整数；Ar1和Ar3相同或不同，是来自四羟基芳香单体的残基，四羟基芳香单体是其中R相同或不同，为H或C1-C8烷基，C2-C8烯基或C3-C8环烷基；Ar2和Ar4相同或不同，是来自四卤代芳香单体的残基，四卤代芳香单体是其中X为F、Cl或Br，且R1和R2相同或不同，其中y为1至8之间的整数；但当Ar1与Ar3相同时，Ar2与Ar4相同，R1和R2不同时为-CN时，可用作气体分离、蒸汽分离、吸附剂或催化剂的材料。
• LADDER POLYMERS WITH INSTRINSIC MICROPOROSITY AND PROCESS FOR PRODUCTION THEREOF
  申请人：Du Naiying

  公开号：US20110190409A1

  公开（公告）日：2011-08-04

  A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C 1 -C 8 alkyl, C2-C8 alkenyl or C 3 -C 8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.
• LADDER POLYMERS WITH INTRINSIC MICROPOROSITY AND PROCESS FOR PRODUCTION THEREOF
  申请人：DU Naiying

  公开号：US20140243441A1

  公开（公告）日：2014-08-28

  A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C 1 -C 8 alkyl, C 2 -C 8 alkenyl or C 3 -C 8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.
• CROSSLINKED POLYMER, METHOD FOR PRODUCING THE SAME, MOLECULAR SIEVE COMPOSITION AND MATERIAL SEPARATION MEMBRANES
  申请人：KYOTO UNIVERSITY

  公开号：US20160367948A1

  公开（公告）日：2016-12-22

  The present invention provides a process for thermal crosslinking of polymers of intrinsic microporosity (PIMs) by heat treatment of PIMs under controlled oxygen concentration.
• US9371429B2
  申请人：——

  公开号：US9371429B2

  公开（公告）日：2016-06-21