dimethyl-(methylsulfanyl-phenyl-methylene)-ammonium; iodide | 6485-11-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dimethyl-(methylsulfanyl-phenyl-methylene)-ammonium; iodide
• 英文别名: dimethyl-(α-methylsulfanyl-benzyliden)-ammonium; iodide；Dimethyl-(α-methylmercapto-benzyliden)-ammonium; Jodid；N,N,S-Trimethyl-thiobenzamidium；Dimethyl-[methylsulfanyl(phenyl)methylidene]azanium;iodide
• CAS: 6485-11-6
• 化学式: C₁₀H₁₄NS*I
• 分子量: 307.198
• InChiKey: XZKQWYKRHDOVRT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.93
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  28.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  dimethyl-(methylsulfanyl-phenyl-methylene)-ammonium; iodide 在 sodium azide 作用下， 以 水 为溶剂， 反应 5.0h， 生成 N,N-dimethyl-1-((methylthio)triaz-2-en-1-ylidene)-1-phenylmethanamine
  参考文献：
  名称：

  Stansfield, Frank, Journal of the Chemical Society. Perkin transactions I, 1984, # 12, p. 2933 - 2935

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N-二甲基苯硫代甲酰胺 、 碘甲烷 生成 dimethyl-(methylsulfanyl-phenyl-methylene)-ammonium; iodide
  参考文献：
  名称：

  合成中高度配位的有机硅化合物：通过使用三甲氧基硅烷和2,3-丁二酸二锂选择性还原烷基硫代甲基亚铵盐，新进入S，N-乙缩醛

  摘要：

  通过在0℃在四氢呋喃中使用三甲氧基硅烷和2，3-丁二酸二锂，可以平稳地还原烷基硫代亚甲基亚氨基碘化物，从而以高收率选择性地得到相应的S，N-乙缩醛。

  DOI：

  10.1016/s0040-4039(00)82188-7

文献信息

• 1,5-Dihydro-1,2,3,4-thia(S IV )triazoles from quaternary salts of NN-disubstituted thioamides and sodium azide
  作者：Susan I. Mathew、Frank Stansfield

  DOI：10.1039/p19740000540

  日期：——

  Quaternary salts [e.g.(I)] of disubstituted thioamides react with aqueous sodium azide at room temperature giving high yields of products which are probably 1,5,5-trisubstituted 1,5-dihydro-1,2,3,4-thia(SIV)triazoles [e.g.(III)]. These are decomposed by dilute acids with loss of nitrogen giving amidines [e.g.(VII)] and thiosulphinic S-esters [e.g.(VIII)]. When the thiatriazole (III) is heated in solution

  二取代硫代酰胺的季盐[例如（I）]在室温下与叠氮化钠水溶液反应，可高收率得到大约为1,5,5-三取代的1,5-二氢-1,2,3,4-硫杂（S IV）三唑[例如（III）]。它们被稀酸分解而失去氮，得到giving [例如（VII）]和硫磺S-酯[例如（VIII）]。当将噻三唑（III）在甲苯或环己烯中的溶液中加热时，分别形成苯甲醛或环己-2-烯酮的二硫缩醛。
• Boettcher; Bauer, Justus Liebigs Annalen der Chemie, 1950, vol. 568, p. 227,237
  作者：Boettcher、Bauer

  DOI：——

  日期：——
• 777. Antituberculous compounds. Part X. Some reactions of quaternary compounds derived from NN-disubstituted thioamides
  作者：D. A. Peak、F. Stansfield

  DOI：10.1039/jr9520004067

  日期：——
• The reactions of isothioamides and thioamidium iodides
  作者：Teruaki Mukaiyama、Syohachi Ono

  DOI：10.1016/s0040-4039(00)75501-8

  日期：1968.1
• Synthese, Struktur und Reaktivität des Ferrioarsaalkens [(η5-C5Me5)(CO)2FeAs=C(Ph)NMe2]
  作者：L. Weber、S. Kleinebekel、P. Lönnecke

  DOI：10.1002/1521-3749(200105)627:5<863::aid-zaac863>3.0.co;2-j

  日期：2001.5

  Reaction of equimolar amounts of the carbenium iodide [Me2N(Ph)CSMe]I and LiAs(SiMe3)(2) . 1.5THF afforded the thermolabile arsaalkene Me3SiAs = C(Ph)NMe2 (1), which in situ was converted into the black crystalline ferrioarsaalkene [(eta (5)-C5Me)(Co)(2)FeAs=C(Ph)NMe2)] (2) by treatment with [(eta (5)-CSMe2)(CO)(2)FeCl]. Compound 2 was protonated by ethereal HBF4 to yield [(eta (5)-CsMe5)(Co)(2)FeAs(H)C(Ph)NMe2] BF4 (3) and methylated by CF3SO3Me to give [(eta (5)-C5Me5)(CO)(2)Fe As(Me)C(Ph)NMe2] - SO3CF3 (4). [(eta (5)-C5Me5)(Co)(2)FeAs[M(CO)(n)]C(Ph)NMe2] (5: [M(CO)(n)] = [Fe(CO)(4)]: 6: [Cr(CO)(5)]) were isolated from the reaction of 2 with [Fe-2(CO)PI or [(Z)-cyclooctene}Cr(CO)(5)], respectively. Compounds 2-6 were characterized by means of elemental analyses and spectroscopy (IR, H-1, C-13H-1}-NMR). The molecular structure of 2 was determined by X-ray diffraction analysis.