trans-[FeL(4-amino-3-(p-chlorophenyl)-5-(2-pyridyl)-1,2,4-triazole)₂(NCS)₂] | 1418215-96-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-[FeL(4-amino-3-(p-chlorophenyl)-5-(2-pyridyl)-1,2,4-triazole)₂(NCS)₂]
• CAS: 1418215-96-9
• 化学式: C₂₈H₂₀Cl₂FeN₁₂S₂
• 分子量: 715.432
• InChiKey: BSCORUJXCRQDCH-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  trans-[Fe(4-amino-3-(p-chlorophenyl)-5-(2-pyridyl)-1,2,4-triazole)₂(NCS)₂][Fe(4-amino-3-(p-chlorophenyl)-5-(2-pyridyl)-1,2,4-triazole)₂(CH₃OH)₂](NCS)₂ 反应 0.5h， 以97.8%的产率得到trans-[FeL(4-amino-3-(p-chlorophenyl)-5-(2-pyridyl)-1,2,4-triazole)₂(NCS)₂]
  参考文献：
  名称：

  Coexistence of two distinct axial ligands and their thermo-induced substitution in trans-[FeL2(NCS)2][FeL2(CH3OH)2](NCS)2 (L=4-amino-3-(p-chlorophenyl)-5-(2-pyridyl)-1,2,4-triazole)

  摘要：

  A novel iron(II) complex, trans-[FeL2(NCS)(2)][FeL2(CH3OH)(2)](NCS)(2) (1) with 4-amino-3-(p-chlorophenyl)-5-(2-pyridyl)-1,2,4-triazole (L) has been successfully synthesized and characterized. X-ray crystallography analysis shows that 1 is the first example in the mononuclear triazole-based complexes consisting of two distinct molecules: trans-[FeL2(NCS)(2)] and trans-[FeL2(CH3OH)(2)](NCS)(2) with each octahedral iron(II) center coordinated axial by two NCS- ions in Fe1 but two MeOH molecules in Fe2. Moreover, 1 can lose two MeOH molecules at 220 degrees C to form trans-[FeL2(NCS)(2)] (2) which can be transformed to 1 when recrystallizing 2 in methanol. Both 1 and 2 are high-spin species in the range of 1.8-300 K. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2012.11.022