bisiodobis(diisopropyldithiocarbamato)tellurium(IV) | 132829-15-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: bisiodobis(diisopropyldithiocarbamato)tellurium(IV)
• CAS: 132829-15-3
• 化学式: C₁₄H₂₈I₂N₂S₄Te
• 分子量: 734.063
• InChiKey: GGAMBSICCIXHRQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  tellurium(IV)(diisopropyldithiocarbamate)4 在 I₂ 作用下， 以 二氯甲烷 为溶剂， 生成 bisiodobis(diisopropyldithiocarbamato)tellurium(IV)
  参考文献：
  名称：

  Synthesis and structure of bisiodobis(diisopropyldithiocarbamato)tellurium(IV)

  摘要：

  The title mixed ligand complex was synthesized by the controlled oxidative displacement reaction of TeL4" by iodine (L" is diisopropyldithiocarbamate ion). Its crystals are monoclinic, space group P2l with Z = 2 in a unit cell of dimensions a = 8.344(4), b = 14.113(8), c = 10.647(5) angstron, beta = 99.884(2)-degrees, and V = 1235.15 Angstron 3, final R = 0.043 and R(w) = 0.047 for 3553 unique reflections. The central tellurium atom shows a S4I2 six coordination with the two dithiocarbamate groups almost isobidentate, the average Te-S and the Te-I distances being 2.571(3) and 3.011(1) angstron, respectively. The structure is monomeric in the solid state. No intermolecular short contacts are observed.

  DOI：

  10.1007/bf01158977