(isopropylisocyanide)gold(I) p-tolylthiosulfonate | 574704-50-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (isopropylisocyanide)gold(I) p-tolylthiosulfonate
• CAS: 574704-50-0
• 化学式: C₁₁H₁₄AuNO₂S₂
• 分子量: 453.336
• InChiKey: CZWZPAWMOQMJIY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (isopropylisocyanide)gold(I) chloride 、 silver p-tolylthiosulfonate 以 二氯甲烷 为溶剂， 以93%的产率得到(isopropylisocyanide)gold(I) p-tolylthiosulfonate
  参考文献：
  名称：

  Gold(I) thiosulfonate complexes

  摘要：

  A series of seven gold(I) p-tolylthiosulfonate complexes of the general type (L)Au-SS(O)(2)C6H4-4-Me have been prepared from the reaction of silver p-tolylthiosulfonate with the corresponding precursor complexes (L)AuCl in dichloromethane. Yields in excess of 90% were obtained throughout for tertiary phosphine and isocyanide ligands L = PMe3, PPh3, Ph-2(2-Py)P, (4-Me2NC6H4)Ph2P, (PrNC)-Pr-i, and (BuNC)-Bu-t. The complexes are surprisingly stable and undergo controlled decomposition well above 100 C. The crystal and molecular structures have been determined for three representative examples. The Me;P and Ph3P Complexes form dimers with short aurophilic bonding [Au-Au 2.9955(3) and 3.0509(2) Angstrom] in a crossed-swords conformation, while for the (BuNC)-Bu-t complex the monomers with their linear five-atom axes appear as only loosely aggregated dimers with a parallel head-to-tail arrangement [Au-Au 3.5423(3) Angstrom]. In all cases the p-tolylthiosulfonate ligand is S-bonded to the metal center. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01445-7