5,15-dimorpholino-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato zinc(II) | 1159608-06-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5,15-dimorpholino-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato zinc(II)
• CAS: 1159608-06-6
• 化学式: C₅₆H₆₆N₆O₂Zn
• 分子量: 920.569
• InChiKey: XGPPKRCVKISTMA-FFXOGQFOSA-N

反应信息

• 作为产物：
  描述：

  5,15-dimorpholino-10,20-bis-(3,5-di-tertbutylphenyl)porphyrin 在 zinc diacetate 作用下， 以 甲醇 、 氯仿 为溶剂， 反应 1.5h， 以68%的产率得到5,15-dimorpholino-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato zinc(II)
  参考文献：
  名称：

  Metal catalyst-free amination of meso-bromoporphyrins: an entry to supramolecular porphyrinoid frameworks

  摘要：

  meso-Bromoporphyrins can be conveniently substituted by primary and secondary amines in a metal catalyst-free reaction which gives access to a large variety of meso-N-substituted derivatives. In some cases, considerable acceleration of this amination can be effected under microwave irradiation. The amino anchor on the porphyrin skeleton is useful for constructing novel self-assembling porphyrinoids as demonstrated by a single crystal X-ray analysis as well as stationary absorption and fluorescence spectroscopies. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.02.039