(酞菁)双(吡啶)锰(II) | 77648-32-9

• 分子结构分类: 有机化合物 - 苯类化合物
• 中文名称: (酞菁)双(吡啶)锰(II)
• 英文名称: (phthalocyaninato)bis(pyridine)manganese(II)
• 英文别名: bis(pyridine)(phthalocyaninato)manganese；manganese(II)phthalocyanine(pyridine)2
• CAS: 77648-32-9
• 化学式: C₄₂H₂₆MnN₁₀
• 分子量: 725.673
• InChiKey: XWNYAZIWOVQTME-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (酞菁)双(吡啶)锰(II) 以 neat (no solvent) 为溶剂， 生成 酞氰镁
  参考文献：
  名称：

  Hanack, Michael; Datz, Arnim, Chemische Berichte, 1986, vol. 119, # 4, p. 1281 - 1290

  摘要：

  DOI：
• 作为产物：
  描述：

  酞氰镁 在 吡啶 作用下， 以 吡啶 为溶剂， 生成 (酞菁)双(吡啶)锰(II)
  参考文献：
  名称：

  Hanack, Michael; Datz, Arnim, Chemische Berichte, 1986, vol. 119, # 4, p. 1281 - 1290

  摘要：

  DOI：

文献信息

• Synthesis, structural investigations and magnetic properties of dipyridinated manganese phthalocyanine, MnPc(py)2
  作者：Jan Janczak、Ryszard Kubiak、Małgorzata Śledź、Horst Borrmann、Yuri Grin

  DOI：10.1016/s0277-5387(03)00361-9

  日期：2003.8

  The MnPc(py)(2) complex was obtained in the reaction of MnPc with purified and dry pyridine under non-oxidation conditions. It crystallises in the centrosymmetric space group P2(1)/c of the monoclinic system with two molecules per unit cell. The Mn2+ cation is coordinated by four N-isoindole atoms of phthalocyaninato(2-) macrocycle and axially by two nitrogen atoms of pyridine molecules into a tetragonal bipyramid. The MnPC(py)(2) crystals are moderately stable under air, but in pyridine solution the MnPC(py)2 complex undergoes oxidation by O-2 Yieldings the binuclear manganese(III) mu-oxo complex (MnPcpy)(2)O as evidenced by the UV-Vis spectroscopy. The magnetic susceptibility measurement performed on solid sample of MnPC(py)(2) shows the Curie-Weiss behaviour in the temperature region of 300-15 K. The calculated magnetic moment mu(eff) indicates three impaired electrons (S = 3/2), thus the ground state configuration of Mn ion is (a(Ig))(2)(e(g))(2)(b(2g))(1), and the MnPc(py)(2) complex is the intermediate spin complex. Below 5.5 K (T-N) the magnetic susceptibility sharply decreases due to the cooperative intermolecular antiferromagnetic interactions. (C) 2003 Elsevier Ltd. All rights reserved.
• Photoreactivity of μ-oxobis(phthalocyanatoiron(III) and μ-oxobis(phthalocyanatomanganese(III))
  作者：A.B.P. Lever、S. Licoccia、B.S. Ramaswamy

  DOI：10.1016/s0020-1693(00)90287-1

  日期：1982.1