bis(9,9-dimethyl-7-phenyl-9H-fluoren-2-yl)amine | 1245939-48-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: bis(9,9-dimethyl-7-phenyl-9H-fluoren-2-yl)amine
• 英文别名: N-(9,9-dimethyl-7-phenyl-9H-fluoren-2-yl)-9,9-dimethyl-7-phenyl-9H-Fluoren-2-amine；N-(9,9-dimethyl-7-phenylfluoren-2-yl)-9,9-dimethyl-7-phenylfluoren-2-amine
• CAS: 1245939-48-3
• 化学式: C₄₂H₃₅N
• 分子量: 553.747
• InChiKey: OZTMWXMUUVDOAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.7
• 重原子数：
  43
• 可旋转键数：
  4
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-溴三蝶烯 、 bis(9,9-dimethyl-7-phenyl-9H-fluoren-2-yl)amine 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 2.0h， 以72%的产率得到
  参考文献：
  名称：

  유기전기소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치

  摘要：

  本发明涉及用于有机电子器件的化合物，以及使用该化合物的有机电子器件和包含该有机电子器件的电子设备。根据本发明，可以提供具有高发光效率、低驱动电压和耐高温的有机电子器件，并可以改善有机电子器件的颜色纯度和寿命。

  公开号：

  KR20210100352A

文献信息

• MATERIALS FOR ORGANIC ELECTROLUMINESCENT DEVICES
  申请人：Merck Patent GmbH

  公开号：US20190119260A1

  公开（公告）日：2019-04-25

  The present invention describes amines with dibenzofuran or dibenzothiophene groups in combination with carbazole, especially for use as triplet matrix materials in organic electroluminescent devices. The invention further relates to a process for preparing the compounds of the invention and to electronic devices comprising these compounds.

  本发明描述了带有二苯并呋喃或二苯并噻吩基团的胺类化合物与咔唑的组合，特别用作有机电致发光器件中的三重态基质材料。该发明还涉及一种制备本发明化合物的方法，以及包含这些化合物的电子器件。
• AROMATIC AMINE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT ELEMENTS USING SAME
  申请人：KATO Tomoki

  公开号：US20120146014A1

  公开（公告）日：2012-06-14

  Provided are an organic EL device material that reduce the driving voltage of an organic EL device and increase the lifetime of the device as compared with a conventional organic EL device material. Also provided are organic electroluminescence devices containing the organic EL device material.

  提供了一种有机EL器件材料，与传统有机EL器件材料相比，该材料降低了有机EL器件的驱动电压并增加了器件的使用寿命。同时，还提供了含有该有机EL器件材料的有机电致发光装置。
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2415752A1

  公开（公告）日：2012-02-08

  There are provided an aromatic monoamine derivative having a fluorene structure-containing organic group and an aromatic hydrocarbon group-containing organic group, and an organic electroluminescent element containing an organic thin film layer composed of a single layer or plural layers while including at least a light emitting layer, the organic thin film layer being between a cathode and an anode, wherein at least one layer of the organic thin film layer, particularly a hole transport layer, contains the aromatic amine derivative alone or as a component of a mixture. An organic electroluminescent element which maintains high luminous efficiency even if exposed to a high temperature environment, and has a low driving voltage and a long emission lifetime, and an aromatic amine derivative capable of realizing the organic electroluminescent element are provided.

  提供了一种具有含芴结构有机基团和含芳香烃基团有机基团的芳香族单胺衍生物，以及一种有机电致发光元件，该元件包含由单层或多层组成的有机薄膜层，同时至少包括一个发光层，该有机薄膜层位于阴极和阳极之间，其中该有机薄膜层的至少一层，特别是空穴传输层，单独含有芳香族胺衍生物或作为混合物的组分。本发明提供了一种即使暴露在高温环境中也能保持高发光效率、低驱动电压和长发射寿命的有机电致发光元件，以及一种能够实现该有机电致发光元件的芳香胺衍生物。
• Aromatic amine derivatives and organic electroluminescent elements using same
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10355218B2

  公开（公告）日：2019-07-16

  Provided are an organic EL device material capable of reducing the driving voltage of an organic EL device and increasing the lifetime of the device as compared with a conventional organic EL device material, specifically an aromatic amine derivative represented by N(Ara)(Arb)(Arc), and an organic EL device using the material. [Ara is represented by the formula (II). (In the formula (II): La represents a single bond or an arylene group; R1 to R4 each represent an alkyl group, an aryl group, or the like, and R3's or R4's, or R3 and R4 may be bonded to each other to form a ring; and o represents 0 to 3 and p represents 0 to 4.) Arb is represented by the formula (III). (in the formula (III), X represents NRa, O, or S, and Ra and R5 to R7 each represent an alkyl group, an aryl group, or the like, and R5's, R6's, or R7's adjacent to each other, or R5 and R6 may be bonded to each other to form a ring; n represents 2 to 4 when X represents NRa, and represents 0 to 4 when X represents O or S; and q represents 0 to 3, r and s each independently represent 0 to 4.) Arc represents an aryl group, or is represented by the formula (III)].

  本发明提供了一种有机电致发光器件材料，与传统的有机电致发光器件材料相比，该材料能够降低有机电致发光器件的驱动电压并延长该器件的使用寿命，特别是一种由 N(Ara)(Arb)(Arc)代表的芳香胺衍生物，以及一种使用该材料的有机电致发光器件。[Ara 由式（II）表示。(在式（II）中La 代表单键或芳基；R1 至 R4 各自代表烷基、芳基或类似基团，R3 的或 R4 的或 R3 和 R4 可相互键合形成环；o 代表 0 至 3，p 代表 0 至 4）。Arb 由式（III）表示。(在式(III)中，X 代表 NRa、O 或 S，Ra 和 R5 至 R7 各自代表烷基、芳基或类似基团，且 R5、R6 或 R7 彼此相邻，或 R5 和 R6 可彼此键合形成环；当 X 代表 NRa 时，n 代表 2 至 4，当 X 代表 O 或 S 时，n 代表 0 至 4；且 q 代表 0 至 3，r 和 s 各自独立地代表 0 至 4)。Arc 代表芳基，或由式 (III)] 表示。
• Materials for organic electroluminescent devices
  申请人：Merck Patent GmbH

  公开号：US10961230B2

  公开（公告）日：2021-03-30

  The present invention describes amines with dibenzofuran or dibenzothiophene groups in combination with carbazole, especially for use as triplet matrix materials in organic electroluminescent devices. The invention further relates to a process for preparing the compounds of the invention and to electronic devices comprising these compounds.

  本发明描述了具有二苯并呋喃或二苯并噻吩基团的胺与咔唑的组合，特别是用作有机电致发光器件中的三重基质材料。本发明还涉及制备本发明化合物的工艺以及包含这些化合物的电子器件。