Ni(o-phenylenediamine)2Cl2 | 17029-47-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Ni(o-phenylenediamine)2Cl2
• 英文别名: [nickel(II)Cl2(1,2-diaminobenzene)2]；benzene-1,2-diamine;nickel(2+);dichloride
• CAS: 17029-47-9
• 化学式: C₁₂H₁₆Cl₂N₄Ni
• 分子量: 345.882
• InChiKey: XVHNENINICDRJM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -4.29
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  104
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Ni(o-phenylenediamine)2Cl2 、 邻苯二甲醛 以 甲醇 为溶剂， 以67%的产率得到dichloro[3,4,7,8,11,12,15,16-tetrabenzo-2,5,10,13-tetraazacyclohexadecane-1,5,9,13-tetraene]nickel(II)
  参考文献：
  名称：

  Metal ion-directed synthesis of 16-membered tetraazamacrocyclic complexes and their physico-chemical studies

  摘要：

  Complexes of Co(II), Ni(II), Cu(II) and Zn(II) containing macrocyclic tetradentate nitrogen donor (N-4) ligand have been synthesized from the template condensation reaction between o-phthalaldehyde and o-phenylenediamine. The newly synthesized ligand and its complexes have been characterized on the basis of results of elemental analysis, molar conductance, magnetic susceptibility measurements, FT-IR, electronic, H-1 FT NMR spectral data and Job's method. Their thermal behaviour has been studied by the thermogravimetric analysis. An octahedral geometry has been proposed for all of these complexes except the copper complexes, which show distorted octahedral geometry. The low conductivity data suggest their non-ionic nature. The biological activities of the metal complexes have also been studied against different bacteria. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.07.050
• 作为产物：
  描述：

  邻苯二胺 、 nickel(II) chloride hexahydrate 以 甲醇 为溶剂， 生成 Ni(o-phenylenediamine)2Cl2
  参考文献：
  名称：

  Synthesis, Spectral Characterization and Biological Evaluation of Glutaric acid based Macrocyclic Complexes

  摘要：

  在二价过渡金属离子以氯化物形式存在的情况下，利用戊二酸和邻苯二胺设计并合成了一系列独特的大环配合物。利用紫外-可见光、红外光谱、ESR 和 ESI-MS 光谱方法分析了这些新设计的配合物。为了评估它们的热行为，还采用了 TGA 分析法。生成的配合物的通式为 [M(L)X2]（L = 配体，X = Cl-，M = Co2+、Ni2+ 和 Cu2+）。中心金属离子被八面体环境包围。测试了这些大环复合物对所选细菌菌株（金黄色葡萄球菌、枯草芽孢杆菌、绿脓杆菌和大肠杆菌）以及真菌菌株（黑曲霉和白色念珠菌）的抗菌效果，并分别将其药效与标准药物链霉素和伊曲康唑进行了比较。此外，还使用 DPPH 法评估了大环复合物的抗氧化活性。

  DOI：

  10.14233/ajchem.2023.28087

文献信息

• Crystal structure and electrical conductivity of nickel 6, 13-di (p-tolyl)-5, 14-dihydrodibenzo [b,i]-1,4,8,11-tetraaza [14]annulene Iodide (Ni (dtdbtaa)I2.58)
  作者：Max Hunziker、Hans Loeliger、Grety Rihs、Bruno Hilti

  DOI：10.1002/hlca.19810640810

  日期：1981.12.16

  Single crystals of the title compound are monoclinic, space group P21/n with two formula units per cell of the following dimensions: a = 18.209, b = 19.076, c = 4.075 Å, β = 92.43°. The crystals show metallic conductivity along the needle axis from room temperature down to ca. 180 K, the maximum conductivity at room temperature being 455 (Ω cm)−1.

  标题化合物的单晶为单斜晶系，空间群P2 1 / n，每个晶胞具有以下两个尺寸的以下分子式：a = 18.209，b = 19.076，c = 4.075，β= 92.43°。晶体从室温到大约℃沿针轴显示出金属导电性。180 K，室温下的最大电导率为455（Ωcm）-1。
• Synthesis and catalytic activity of novel Ni-N complexes
  作者：L. Mei、F. H. Tao、D. Long、Z. S. Ming、L. X. Liang、L. Q. Rong

  DOI：10.1134/s1070328412080088

  日期：2012.8

  A series of nickel complexes with 1,3-xylylenediamine, 1,2-diaminobenzene and 1,2-aminobenzylamine were first synthesized and characterized. The reaction of these amines with Ni(OAc)(2) center dot 4H(2)O and NiCl2 center dot 6H(2)O in methanol or tetrahydrofuran resulted in the production of four novel nickel complexes I, II, III, and IV. The structure of each complex was determined by X-ray diffraction analysis. Each complex was also characterized using elemental analysis, H-1 NMR and IR. The complexes were then used to catalyze the Henry reaction, and good catalytic results (65-99%) were achieved. The catalytic activity of the complexes was determined by H-1 NMR.
• TEMPLATE SYNTHESIS OF TWO NEW GLYOXIME DERIVATIVES. CHARACTERIZATION AND INVESTIGATION OF THEIR COMPLEXES WITH Ni(II), Cu(II), AND Co(II) METAL IONS
  作者：Mükerrem Kurtoğlu、Selahattin Serin

  DOI：10.1081/sim-100106853

  日期：2001.8.31

  Two novel oximes containing di- and tetraoxime groups, dichloro-[N,N'-bis(2-aminophenyl)diaminoglyoxime]nickel(II), [Ni(LH2)Cl-2], and dichloro-[5,6:11,12-dibenzo-2,3,8,9-tetra(hydroxyimino)-1,4,7,10-tetraazacyelododecane]}- nickel(II), [Ni(LH4)Cl-2], have been synthesized by the template condensation reaction of dichloro-[N,N'-bis-(1,2-diaminobenzene)]nickel(II) with anti-dichloroglyoxime. Trinuclear complexes of [Ni(LH2)Cl-2] with Ni(II), Cu(II) and Co(II) have been synthesized. A polynuclear complex of [Ni(LH4)Cl-2] with Ni(II) has been prepared. The structures of these novel oxime compounds are proposed on the basis of the elemental analyses, IR and UV-Visible spectra and conductivity measurements. Conductivity measurements have shown that all complexes are non-electrolytes.