| 319015-22-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 319015-22-0
• 化学式: CH₂Cl₂*C₄₈H₄₀N₂OP₄Se₄V
• 分子量: 1236.47
• InChiKey: KGGXAJWDFFTWJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.48
• 重原子数：
  63.0
• 可旋转键数：
  8.0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.02
• 拓扑面积：
  41.79
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  [VCl3(thf)3] 、 二氯甲烷 、 水 、 potassium bis(diphenylselenophosphoryl)amide 以 二氯甲烷 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Syntheses and characterization of imidodiphosphinoselenido complexes of V(IV), V(III), and Cr(III): [VO{N(SePPh2)2}2]·CH2Cl2, [V{N(SePPh2)2}3]·CH2Cl2, and [Cr{N(SePPh2)2}3]·CH2Cl2

  摘要：

  The imidodiphosphinoselenido complexes of V(IV), V(III), and Cr(III), [VO{N(SePPh2)(2)}]. CH2Cl2 (1), [V{N(SePPh2)(2)}(3)]. CH2Cl2 (2), and [Cr{N(SePPh2)(2)}(3)]. CH2Cl(2) (3), have been prepared from the reaction between VCl2(THF)(3) (1 and 2) or CrCl2 (3) and K[N(SePPh2)(2)] in CH2Cl2. These compounds have been characterized by single-crystal X-ray diffraction and spectroscopic techniques as well as by a magnetic susceptibility measurement for 3. In each of these compounds the [N(SePPh2)(2)](-) ligand exhibits an Se,Se,Se-bonding chelation to the metal center. In 1, two ligands are coordinated to a VO2+ unit to afford a pyramidal environment about V; in 2 and 3, three ligands are coordinated to each metal center to afford an octahedral geometry. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00219-x