Zn(bpdtc)2 | 796975-38-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Zn(bpdtc)2
• 英文别名: zinc;N-butyl-N-phenylcarbamodithioate
• CAS: 796975-38-7
• 化学式: C₂₂H₂₈N₂S₄Zn
• 分子量: 514.132
• InChiKey: LAGTXXPOZSLGSF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.25
• 重原子数：
  29
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  72.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,2'-联吡啶 、 Zn(bpdtc)2 以 氯仿 为溶剂， 以80%的产率得到Zn(bpdtc)2(bpy)
  参考文献：
  名称：

  双（N-烷基-N-苯基二硫代氨基甲酸）锌 (II) 的 2,2'-联吡啶加合物的合成、光谱和热研究

  摘要：

  摘要 合成了三种N-烷基-N-苯基二硫代氨基甲酸酯与2,2'-联吡啶的Zn(II)加合物，并通过元素分析和光谱技术对其进行了表征。这些化合物的公式为 [Zn(mpdtc) 2 bpy] ( 1 )、[Zn(epdtc) 2 bpy] ( 2 ) 和 [Zn(bpdtc) 2 bpy] ( 3 )（其中 m = 甲基，e = 乙基, b = 丁基；p = 苯基且 bpy = 2,2'-联吡啶）。还报道了化合物(1)和(2)的单晶X射线结构。结果表明，化合物(1)以五配位三角双锥体结构存在，其中一个二硫代氨基甲酸酯作为螯合配体，另一个占据顶端位置作为单齿配体，而化合物(2)作为六配位八面体物种存在。两种化合物中的每一种在晶胞中都有四个分子，配合物 1 中未配位的 S 原子参与弱 C–H⋯S 相互作用。还报告了化合物的热分解曲线。

  DOI：

  10.1016/j.molstruc.2010.11.060

文献信息

• Flame retardant rubber composition, rubber articles and wire covering materials
  申请人：Morioka Seiji

  公开号：US20060111504A1

  公开（公告）日：2006-05-25

  A flame retardant rubber composition includes (A) an ethylene/α-olefin random copolymer, (B) an unsaturated nitrile/conjugated diene rubber, and (D) surface-treated natural magnesium hydroxide or includes (A) an ethylene/α-olefin random copolymer, (B) an unsaturated nitrile/conjugated diene rubber, (C) a hydrogenated diene polymer, and (D) surface-treated natural magnesium hydroxide. Since the rubber composition and rubber product have good flame retardance, weather resistance, and oil resistance, as well as excellent mechanical characteristics, they are useful for various applications such as a roll, belt, and sealing material for copying machines, an electric wire coating material, and hoses.

  一种阻燃橡胶组合物，包括（A）乙烯/α-烯烃随机共聚物，（B）不饱和腈/共轭二烯橡胶，以及（D）经过表面处理的天然氢氧化镁，或包括（A）乙烯/α-烯烃随机共聚物，（B）不饱和腈/共轭二烯橡胶，（C）氢化二烯聚合物，以及（D）经过表面处理的天然氢氧化镁。由于橡胶组合物和橡胶制品具有良好的阻燃性、耐候性、耐油性以及优异的机械特性，因此它们适用于各种应用，如复印机的卷筒、传送带和密封材料、电线涂层材料和软管。
• Olefin block copolymers processes for producing the same and uses thereof
  申请人：——

  公开号：US20030055179A1

  公开（公告）日：2003-03-20

  The present invention provides polymers having any one of properties including affinity for metals or polar resins, impact resistance, mar resistance, heat resistance, rigidity, oil resistance, transparency, anti-fogging properties, electric insulating properties, high breakdown voltage, coating properties, low-temperature flexibility, moldability, environmental degradation, fluidity and dispersibility, and provides a process for preparation thereof. The olefin block copolymers (A-1) of the invention are represented by the formula (I) PO 1 —g 1 —B 1 (I) (wherein PO 1 is a segment composed of repeating units derived from an olefin having 2 to 20 carbon atoms, g 1 is an ester, ether, amide, imide, urethane, urea, silylether or carbonyl linkage, and B 1 is a segment containing an unsaturated hydrocarbon or a hetero atom). The olefin block copolymers are suitable for uses in adhesives; various molded articles such as construction and civil engineering materials, automobile interior and exterior materials, gasoline tanks, electric and electronic parts, medical care and sanitation materials, materials of miscellaneous goods, resin materials having environmental degradation properties, films and sheets; modifiers and dispersions.

  本发明提供了具有以下任一性质的聚合物，包括对金属或极性树脂的亲和性，抗冲击性，抗刮伤性，耐热性，刚度，耐油性，透明性，防雾性能，电绝缘性能，高击穿电压，涂料性能，低温柔性，可塑性，环境降解性，流动性和分散性，并提供其制备方法。本发明的烯烃嵌段共聚物（A-1）由公式（I）表示：PO1-g1-B1（I）（其中PO1是由具有2至20个碳原子的烯烃衍生的重复单元组成的片段，g1是酯，醚，酰胺，亚胺，脲，硅醚或羰基连接，B1是含有不饱和碳氢化合物或杂原子的片段）。烯烃嵌段共聚物适用于粘合剂；各种成型品，如建筑和土木工程材料，汽车内外饰料，汽油箱，电子和电气零件，医疗保健和卫生材料，杂货物料，具有环境降解性能的树脂材料，薄膜和片材；改性剂和分散剂。
• Chlorinated rubber and polyvinyl chloride composition containing the same
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0091973A1

  公开（公告）日：1983-10-26

  A chlorinated rubber having a chlorine content of about 5 through about 50% by weight and a Mooney viscosity (ML1+4at 100°C) of about 20 through about 150 is presented. This chlorinated rubber is derived from the chlorination of (i) a copolymer rubber of ethylene and 1-butene having a mol ratio of ethylene/1-butene of about 85/15 through about 95/5 or (ii) a copolymer rubber of ethylene 1-butene and 5-ethylidene-2-norbornene having a mol ratio of ethylene/1-butene of about 85/15 through about 95/5 and a content of the 5-ethylidene-2-norbornene of 20% by weight or less based on the weight of the copolymer. The incorporation of the chlorinated rubber into a polyvinyl chlorid composition results in the remarkable improvement of the impact resistance and flexibility, both at a low temperature, of the polyvinyl chloride.

  介绍一种氯化橡胶，其氯含量约为 5%至 50%（按重量计），门尼粘度（100°C 时 ML1+4）约为 20 至 150。这种氯化橡胶由以下橡胶氯化而成：(i) 乙烯和 1-丁烯的共聚橡胶，乙烯/1-丁烯的摩尔比约为 85/15 至约 95/5；或 (ii) 乙烯-1-丁烯和 5-亚乙基-2-降冰片烯的共聚橡胶，乙烯/1-丁烯的摩尔比约为 85/15 至约 95/5，5-亚乙基-2-降冰片烯的含量为共聚物重量的 20%或以下。在聚氯乙烯组合物中加入氯化橡胶，可显著提高聚氯乙烯在低温下的抗冲击性和柔韧性。
• Ethylene-alpha-olefin-polyene random copolymer rubber
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0094051A1

  公开（公告）日：1983-11-16

  An ethylene-alpha-olefin-polyene random copolymer rubber comprising ethylene, an alpha-olefin having 3 to 10 carbon atoms and a ployene,wherein (A)a molar ratio of ethylene/al-p-ha-olefin is 55/45 to 95/5, (B) the polyene is a mixture of 5- ethyitdene-2-norbornene (ENB) and 5-vinyl-2-norbornene (VNB) in a molar ratio of ENB/VNB of 1/1 to 20/1, (C) an iodine value of the copolymer rubber is 2 to 40, (D) an intrinsic viscosity [η] of the copolymer rubber is 1.0 to 6.0 dl/g measured in decalin at 135°C, and (E) gη* defined by a ratio of the intrinsic viscosity [η] to an intrinsic viscosity [η]I of a linear ethylene-propylene random copolymer having an ethylene content of 70 mole% and the same weight-average molecular weight determined by a light-scattering method as that of the copolymer rubber is 0.2 to 0.9. Also a process for preparing this random copolymer rubber and vulcanizate derived from the same are also disclosed. This random copolymer rubber has an excellent extrudability and a fast cure rate and provides a vulcanizate having high tensile strength.

  一种乙烯-α-烯烃-聚烯无规共聚橡胶，包括乙烯、具有 3 至 10 个碳原子的α-烯烃和聚烯，其中 (A) 乙烯/α-烯烃的摩尔比为 55/45 至 95/5、(B) 聚烯是 5-乙基-2-降冰片烯（ENB）和 5-乙烯基-2-降冰片烯（VNB）的混合物，ENB/VNB 的摩尔比为 1/1 至 20/1， (C) 共聚橡胶的碘值为 2 至 40， (D) 共聚橡胶的固有粘度[η]为 1.0 至 6.0 dl/g；(E) 本征粘度[η]与线性乙烯-丙烯无规共聚物的本征粘度[η]I 之比定义的 gη* 为 0.2 至 0.9，线性乙烯-丙烯无规共聚物的乙烯含量为 70 摩尔%，通过光散射法测定的重量平均分子量与共聚橡胶的重量平均分子量相同。此外，还公开了制备这种无规共聚物橡胶和由其衍生的硫化胶的工艺。这种无规共聚物橡胶具有优异的挤出性和快速固化率，并可提供具有高拉伸强度的硫化胶。
• Chlorinated rubber
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0225063A2

  公开（公告）日：1987-06-10

  A chlorinated rubber having a chlorine content of 10 to 45% by weight based on the weight of the chlorinated rubber and a Mooney viscosity, ML1-4 (121°C), of 10 to 190 is obtained by chlorinating an ethylene/alpha-olefin/non conjugated diene copolymer rubber containing 5-vinyl-2-norbornene as the non-conjugated diene. The chlorinated rubber has excellent processability in roll milling, extrusion, etc.

  通过氯化含有 5-乙烯基-2-降冰片烯作为非共轭二烯的乙烯/α-烯烃/非共轭二烯共聚橡胶，可获得一种氯化橡胶，其氯含量（以氯化橡胶重量计）为 10% 至 45%，门尼粘度（ML1-4，121°C）为 10 至 190。 该氯化橡胶在辊磨、挤出等过程中具有出色的加工性能。