4'-氨基-5'-氯-2'-羟基苯甲酰苯胺 | 5099-13-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4'-氨基-5'-氯-2'-羟基苯甲酰苯胺
• 英文名称: N-(4-Amino-5-chloro-2-hydroxy-phenyl)-benzamide
• 英文别名: Benzamide, N-(4-amino-5-chloro-2-hydroxyphenyl)-；N-(4-amino-5-chloro-2-hydroxyphenyl)benzamide
• CAS: 5099-13-8
• 化学式: C₁₃H₁₁ClN₂O₂
• 分子量: 262.696
• InChiKey: HYPJTFZIRMSKAK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  75.4
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-[m-(3-Chloro-2,2,3-trifluoro-propionamido)-phenoxy]-myristoyl chloride 、 4'-氨基-5'-氯-2'-羟基苯甲酰苯胺 生成 N-[5-chloro-4-[2-[3-[(3-chloro-2,2,3-trifluoropropanoyl)amino]phenoxy]tetradecanoylamino]-2-hydroxyphenyl]benzamide
  参考文献：
  名称：

  MONBALIU, MARCEL JACOB;VAN, MEERBEECK PAUL LOUIS

  摘要：

  DOI：
• 作为产物：
  描述：

  5'-氯-2'-羟基-4'-硝基苯甲酰苯胺 生成 4'-氨基-5'-氯-2'-羟基苯甲酰苯胺
  参考文献：
  名称：

  LENTZ, CARL M.;MULLINS, EDWARD T.;GIBSON, CHARLES L.

  摘要：

  DOI：

文献信息

• Hydrogenation of halonitroaromatic compounds
  申请人：Eastman Kodak Company

  公开号：US04929737A1

  公开（公告）日：1990-05-29

  Disclosed is an improved process for the preparation of haloaromatic amines by the catalytic hydrogenation of halonitroaromatic compounds in the presence of a chromium-containing Raney cobalt catalyst. The catalyst gives good hydrogenation rates while minimizing formation of dehalogenated by-products.

  本发明揭示了一种改进的工艺，可通过在含有铬的Raney钴催化剂的存在下对卤代硝基芳香化合物进行催化氢化，制备卤代芳香胺。该催化剂在最小化去卤代副产物的同时，保持良好的氢化速率。
• Light-sensitive silver halide color photographic material containing
  申请人：Konica Corporation

  公开号：US04840883A1

  公开（公告）日：1989-06-20

  There is disclosed a light-sensitive silver halide color photographic material containing novel cyan coupler which comprises a light-sensitive silver halide color photographic material having at least one silver halide emulsion layer on a support, characterized in that at least one layer of the silver halide emulsion layer contains at least one cyan coupler represented by the formula (I) shown below: ##STR1## wherein R.sub.1 and R.sub.2 each represent an alkyl group, an aryl group, a heterocyclic group, a dialkylamino group, an anilino group, an alkoxy group or an arloxy group; R.sub.3 represents a hydrogen atom or an alkyl group; R.sub.4 represents a hydrogen atom, an alkyl group, an aryl group, A R.sub.5 CO--group or a R.sub.5 SO.sub.2 --group; provided that R.sub.3 and R.sub.4 cannot be hydrogen atoms at the same time; R.sub.5 represents a hydrogen atom, an alkyl group, an aryl group, a dialkylamino group, an anilino group, an alkoxy group or an aryloxy group; and X represents a hydrogen atom or an eliminatable group through the reaction with the oxidized product of a color developing agent.

  本发明涉及一种光敏银卤化物彩色摄影材料，其含有一种新型的青色偶合剂。该光敏银卤化物彩色摄影材料包括至少一层银卤化物乳剂层和一种支撑材料，其特征在于所述银卤化物乳剂层中至少含有一种由下式（I）表示的青色偶合剂：##STR1## 其中，R.sub.1和R.sub.2分别表示烷基、芳基、杂环基、二烷基氨基基团、苯胺基、烷氧基或芳氧基；R.sub.3表示氢原子或烷基；R.sub.4表示氢原子、烷基、芳基、AR.sub.5CO-基或R.sub.5SO.sub.2-基；但要求R.sub.3和R.sub.4不能同时为氢原子；R.sub.5表示氢原子、烷基、芳基、二烷基氨基基团、苯胺基、烷氧基或芳氧基；X表示氢原子或可通过与显色剂氧化产物反应而消除的基团。
• 2,5-Diacylaminophenol-type color couplers and photographic elements
  申请人：AGFA-Gevaert, N.V.

  公开号：US04822729A1

  公开（公告）日：1989-04-18

  Cyan-forming color couplers according to the formula: ##STR1## wherein Z is hydrogen or a coupling off group, R.sup.1 is hydrogen, a halogen atom, alkyl, or alkoxy, R.sup.2 is hydrogen or alkyl, R.sub.3 is hydrogen, a halogen atom, alkyl, alkoxy, alkylsulphonyl, alkanamidosulphonyl, alkoxycarbonyl, alkanamidocarbonyl, alkanamido, alkylsulphonamido, or cyano, R.sup.4 is a substituent standing at the 3- or 6-position of the phenol and selected from hydrogen, a halogen atom, and alkyl, and n is 0 or 1. These couplers can be incorporated into (a) red-sensitized silver halide emulsion layer(s) of a photographic multilayer color element or in a non-light-sensitive colloid layer in water-permeable relationship with the red-sensitized emulsion layer(s).

  根据以下公式制备青色形成的色偶合物：##STR1## 其中Z为氢或偶联基，R.sup.1为氢、卤素原子、烷基或烷氧基，R.sup.2为氢或烷基，R.sub.3为氢、卤素原子、烷基、烷氧基、烷基磺酰基、烷基酰胺磺酰基、烷氧羰基、烷基酰胺羰基、烷基酰胺、烷基磺酰胺或氰基，R.sup.4为取代苯酚的3-或6-位上的取代基，选自氢、卤素原子和烷基，n为0或1。这些色偶合物可以被纳入（a）感光红敏银卤化物乳液层的多层彩色元素中的红敏感层或与红敏感乳液层具有水渗透性关系的非感光胶体层中。
• Light-sensitive silver halide color photographic material containing novel cyan coupler
  申请人：KONICA CORPORATION

  公开号：EP0296780A2

  公开（公告）日：1988-12-28

  There is disclosed a light-sensitive silver halide color photographic material containing novel cyan coupler which comprises a light-sensitive silver halide color photographic material having at least one silver halide emulsion layer on a support, characterized in that at least one layer of the silver halide emulsion layer contains at least one cyan coupler represented by the formula (I) shown below: wherein R₁ and R₂ each represent an alkyl group, an aryl group, a heterocyclic group, a dialkylamino group, an anilino group, an alkoxy group or an arloxy group; R₃ represents a hydrogen atom or an alkyl group; R₄ represents a hydrogen atom, an alkyl group, an aryl group, a R₅CO- group or a R₅SO₂- group; provided that R₃ and R₄ cannot be hydrogen atoms at the same time; R₅ represents a hydrogen atom, an alkyl group, an aryl group, a dialkylamino group, an anilino group, an alkoxy group or an aryloxy group; and X represents a hydrogen atom or an eliminatable group through the reaction with the oxidized product of a color developing agent.

  本发明公开了一种含有新型青色耦合剂的感光卤化银彩色感光材料，它包括一种感光卤化银彩色感光材料，该材料在支撑体上具有至少一层卤化银乳剂层，其特征在于该卤化银乳剂层的至少一层含有至少一种由下式(I)表示的青色耦合剂： 其中 R₁ 和 R₂ 各自代表烷基、芳基、杂环基、二烷基氨基、苯胺基、烷氧基或芳基；R₃ 代表氢原子或烷基；R₄ 代表氢原子、烷基、芳基、R₅CO- 基团或 R₅SO₂- 基团；但 R₃ 和 R₄ 不能同时为氢原子；R₅ 代表氢原子、烷基、芳基、二烷基氨基、苯胺基、烷氧基或芳氧基；以及 X 代表氢原子或通过与显色剂的氧化产物反应可消除的基团。
• LENTZ, CARL M.;MULLINS, EDWARD T.;GIBSON, CHARLES L.
  作者：LENTZ, CARL M.、MULLINS, EDWARD T.、GIBSON, CHARLES L.

  DOI：——

  日期：——