| 133793-82-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 133793-82-5；155888-48-5；136655-29-3
• 化学式: C₃₃H₃₀ClN₆Os*F₆P
• 分子量: 881.259
• InChiKey: CSPSQBZBLUFOQA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  锇二(2,2'-联吡啶)氯化物 、 4,4'-(1,3-丙二基)双吡啶 以 乙二醇 为溶剂， 生成
  参考文献：
  名称：

  Electron-transfer study and solvent effects on the formal potential of a redox-active self-assembling monolayer

  摘要：

  Solvent effects on the formal potential of the redox-active self-assembling system [Os(bpy)2(dipy)Cl]1+ (bpy, 2,2'-bipyridine; dipy, 4,4'-trimethylenedipyridine) have been studied in six organic solvents and aqueous solutions. Cyclic voltammetry was used to determine surface coverage and formal potentials and the coulostatic technique (charge injection) to determine double-layer capacitance. The variation of the formal potential with solvent and surface coverage is analyzed within the context of surface activity coefficients. The results seem to indicate that ion-pair formation between perchlorate anions (from supporting electrolyte) and the cationic head groups strongly influences the energetics of the system. An estimate of the standard rate constant for the electron transfer in aqueous solution reveals a very fast electron transfer with a lower limit of the order of 10(5) s-1.

  DOI：

  10.1021/j100176a098