Acrylsaeure-2-phenylamino-ethylester | 21080-21-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Acrylsaeure-2-phenylamino-ethylester
• 英文别名: N-(acryloyloxyethyl)-aniline；2-anilinoethyl prop-2-enoate
• CAS: 21080-21-7
• 化学式: C₁₁H₁₃NO₂
• 分子量: 191.23
• InChiKey: GABWEXRVBMIOFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-苯基乙醇胺 、 对苯二酚 、 对甲苯磺酸 、 丙烯酸 在 无水氯化钙 、 水 、 氯仿 、 sodium hydroxide 、 magnesium sulfate 作用下， 以 乙醇 为溶剂， 生成 Acrylsaeure-2-phenylamino-ethylester
  参考文献：
  名称：

  Conjugated Polymers

  摘要：

  单体M-S具有第一可聚合基团（M），能够形成共轭聚合物，以及第二可聚合基团（S），具有易于加成聚合的双键。M基团的聚合通常是通过电聚合或化学氧化引起的。S基团的聚合也通常是通过自由基机制在M聚合之前、之后或同时引起的。适当的单体包括N-（甲基丙烯酰胺乙基）-苯胺，N-（丙烯酰胺乙基）-苯胺，N-（甲基丙烯酰氧乙基）-苯胺和N-（丙烯酰氧乙基）-苯胺。

  公开号：

  US20110111350A1

文献信息

• Extended use planar sensors
  申请人：CIBA-GEIGY AG

  公开号：EP0625704A2

  公开（公告）日：1994-11-23

  A planar, electrochemical sensor having a substrate, conductive strips deposited on the substrate, and a dielectric layer insulating portions of the conductive strips except those portions which define a working electrode and at least one second electrode. The working electrode may be defined by an open printed region of the dielectric, or by a needle-punched or laser-burned hole or opening in the dielectric which exposes a small region of one of the conductive strips. A solid electrolyte contacting the electrodes is covered by a semipermeable membrane which may comprise an acrylonitrile butadiene copolymer or an acrylate-based copolymer. A sample chamber is defined by the membrane, a cover member, and a gasket therebetween, and has a volume of from about 1 to about 2 ml. The gasket is formulated from the highly cross-linked polymerization product of epichlorohydrin. All sensor components are selected such that a sensor operable for at least 2 days under normal conditions is produced.

  一种平面电化学传感器，具有一个基板、沉积在基板上的导电条和一个绝缘介质层，除了那些限定工作电极和至少一个第二电极的部分外，导电条的其他部分与介质层绝缘。工作电极可由电介质的开放印刷区域或电介质上的针刺或激光烧制的孔或开口来确定，这些孔或开口会露出其中一个导电条的小区域。接触电极的固体电解质被半透膜覆盖，半透膜可由丙烯腈-丁二烯共聚物或丙烯酸酯基共聚物组成。样品室由薄膜、盖件和中间的垫圈构成，容积约为 1 至 2 毫升。密封垫由环氧氯丙烷的高交联聚合产物制成。所有传感器部件都经过精选，这样生产出的传感器在正常条件下至少可工作 2 天。
• Copolymers for membranes in extended use planar sensors
  申请人：Novartis AG

  公开号：EP1489410A2

  公开（公告）日：2004-12-22

  A composition characterized in that it comprises the polymerization product of: at least one monomer corresponding to the formula CH1=C(R1)(COOR2), wherein R1 and R2 are independently selected from hydrogen, hydrocarbon group and alcohol groups; at least one monomer selected from those corresponding to the formulae CH2=(R1)(CONR2R3) and CH2=(R1)(OCOR2). wherein R1, R2 and R3 are independently each selected from hydrogen, hydrocarbon groups and alcohol groups; and at least one nitrile-containing monomer. The polymers are particularly suitable as membranes covering an electrolyte in electrochemical sensors.

  一种组合物，其特征在于包含以下物质的聚合产物 至少一种与式 CH1=C(R1)(COOR2) 相对应的单体，其中 R1 和 R2 独立地选自氢、烃基和醇基； 至少一种选自对应于式 CH2=(R1)(CONR2R3) 和 =(R1)(OCOR2) 的单体，其中 R1、R2 和 R3 各自独立地选自氢、烃基和醇基；以及 至少一种含腈单体。 这些聚合物特别适合用作电化学传感器中覆盖电解质的膜。
• Polymeric membranes and other polymer articles having desired surface characteristics and method for their preparation
  申请人：——

  公开号：US20020155311A1

  公开（公告）日：2002-10-24

  Polymeric articles, including membranes, with surfaces having a desired chemical functionality are created by surface segregation of a branched component blended with a compatible, matrix base component, the branched component having the desired chemical functionality. In particular, hydrophilic surfaces are created via surface segregation of a branched hydrophilic copolymer blended into a polymer matrix. The use of branched molecular architecture provides a thermodynamic mechanism for the segregation of the hydrophilic species to the surface and a means for achieving a high surface coverage of the hydrophilic moiety. The branched hydrophilic copolymer can be defined by a random copolymer including two or more methacrylate or acrylate monomers, at least one of which features a short hydrophilic side chain, such as a polyethylene glycol side chain. The branched hydrophilic copolymer is compatible, and well-entangled, with the acrylate polymer matrix.

  通过将具有所需化学功能性的支化组分与相容的基质基础组分混合进行表面分离，可制成表面具有所需化学功能性的聚合物制品（包括膜），支化组分具有所需化学功能性。特别是，亲水表面是通过与聚合物基体混合的支化亲水共聚物的表面分离而形成的。支化分子结构的使用为亲水性物质在表面上的分离提供了一种热力学机制，也为亲水性分子实现高表面覆盖率提供了一种方法。支化亲水共聚物可由无规共聚物定义，包括两种或两种以上甲基丙烯酸酯或丙烯酸酯单体，其中至少一种单体具有短亲水侧链，如聚乙二醇侧链。支化亲水共聚物与丙烯酸酯聚合物基体相容，并能很好地缠结在一起。
• POLYMERIC MEMBRANES AND POLYMER ARTICLES HAVING HYDROPHILIC SURFACE AND METHOD FOR THEIR PREPARATION
  申请人：MASSACHUSETTS INSTITUTE OF TECHNOLOGY

  公开号：EP0949959A2

  公开（公告）日：1999-10-20
• PREPARATION OF POLYMER ARTICLES HAVING HYDROPHILIC SURFACE
  申请人：MASSACHUSETTS INSTITUTE OF TECHNOLOGY

  公开号：EP0949959B1

  公开（公告）日：2008-07-09