| 139700-51-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 139700-51-9
• 化学式: C₄₅H₅₀N₄P₂PtS
• 分子量: 936.012
• InChiKey: WRDUWRLOBYACNX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  10.59
• 重原子数：
  53.0
• 可旋转键数：
  14.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  22.08
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  cis-{PtCl2(P(NEt2)Ph2)} 、 N,N'-二苯基硫脲 在 Ag₂O 作用下， 以 二氯甲烷 为溶剂， 以51%的产率得到
  参考文献：
  名称：

  Thiadiazatrimethylenemethane and N,N′,P-triphenylphosphonothioic diamide complexes of platinum(II)

  摘要：

  Reaction of N,N'-diphenylthiourea with cis-[PtCl2L2] [L = PPh3, PMePh2, PMe2Ph, PEt2Ph, PPh2(NEt2) or L2 = Ph2PCH2CH2PPh2 (dppe) in the presence of silver(I) oxide gives the thiadiazatrimethylenemethane complexes [activated Pt{SC(=NPh)NPh}L2] an X-ray study on [activated Pt{SC(= NPh)NPh}(PPh3)2] establishing the presence of a flat activated Pt-S-C-N ring. Related activated Pt-S-P-N ring complexes which contain a reactive nucleophilic P = NPh group are formed upon treatment of PhNHP(S) (Ph)NHPh with cis-[PtCl2L2] [L = PPh3, L2 = dppe, Ph2P(CH2)3PPh2 or Ph2P(CH2)4PPh2] and potassium hydroxide. Treatment of [activated Pt{SP(= NPh)(Ph)NPh}L2] with Mel afforded an aminophosphonium salt, whilst with substrates containing either C = O or C = S functionalities new complexes of the type [activated [Pt{SPO(O)(Ph)NPh}L2] or [Pt{SP(S)(Ph)S}L2] were formed respectively.

  DOI：

  10.1039/dt9920000059